Article(id=1276976024873210544, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276975955985961244, articleNumber=null, orderNo=null, doi=10.19540/j.cnki.cjcmm.20251010.201, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1752681600000, receivedDateStr=2025-07-17, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1782384409397, onlineDateStr=2026-06-25, pubDate=1767196800000, pubDateStr=2026-01-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1782384409397, onlineIssueDateStr=2026-06-25, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1782384409397, creator=13701087609, updateTime=1782384409397, updator=13701087609, issue=Issue{id=1276975955985961244, tenantId=1146029695717560320, journalId=1276577828834349082, year='2026', volume='51', issue='1', pageStart='1', pageEnd='300', issueExtLink='null', onlineDate='null', pubDate='1767196800000', pubDateStr='2026-01-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1782384392973, creator='13701087609', updateTime=1782384484405, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1276976339546673871, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276975955985961244, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1276976339546673872, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276975955985961244, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=114, endPage=120, ext={EN=ArticleExt(id=1276976025091314354, articleId=1276976024873210544, tenantId=1146029695717560320, journalId=1276577828834349082, language=EN, title=Two new alkaloids from Corydalis delicatula, columnId=null, journalTitle=Chinese Journal of Traditional Chinese Medicine, columnName=null, runingTitle=null, highlight=null, articleAbstract=

In this study, the total alkaloids of Corydalis delicatula were isolated and purified by a combination of silica gel, aluminum oxide basic column chromatography and other chromatographic techniques. The obtained compounds were structurally identified with the help of modern spectral resolution techniques such as nuclear magnetic resonance (1D/2D NMR), high-resolution mass spectrometry (HR-ESI-MS), and single crystal X-ray diffraction. Nine alkaloids were obtained from the total alkaloids of C. delicatula, encompassing two new compounds, corlicatine (1) and N-methyl-13-oxoprotopine (2), and seven known ones: (+)-ochotensine (3), rupestrine A (4), (+)-ochotensimine (5), oxohydrastinine (6), α-magnoflorine (7), 6, 7-methylenedioxy-N-methylisoquinoline (8), and N-methyl-6, 7-dimethoxyisoquinoline (9). The inhibitory activities of the compounds against acetylcholinesterase were evaluated, with compound 4 exhibiting moderate inhibition. Molecular docking was further performed to elucidate the binding mode of this compound. The results provide a basis for elucidating the medicinal substance basis of C. delicatula.

, authors=null, authorsList=Xin-yue HUANG, Shao-wen XIONG, Yuan-fei LI, Yu-chen JIANG, Jia CUI, Kang LI, Li-mei LI, authorCompany=null, correspAuthors=Li-mei LI, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1276976025301029556, articleId=1276976024873210544, tenantId=1146029695717560320, journalId=1276577828834349082, language=CN, title=娇嫩黄堇中2个新生物碱成分, columnId=1276976014295167305, journalTitle=中国中药杂志, columnName=化学, runingTitle=null, highlight=null, articleAbstract=

该研究通过综合运用硅胶、碱性氧化铝柱色谱等多种色谱技术对娇嫩黄堇总生物碱进行分离和纯化，并借助核磁共振（1D/2D NMR）、高分辨质谱（HR-ESI-MS）及X-射线单晶衍射等现代波谱解析技术对所得单体化合物进行结构鉴定。从娇嫩黄堇的总生物碱中分离鉴定9个生物碱，其中包括2个新化合物corlicatine（1）、N-methyl-13-oxoprotopine（2）和7个已知化合物：（+）-ochotensine（3）、rupestrine A（4）、（+）-ochotensimine（5）、oxohydrastinine（6）、α-magnoflorine（7）、6，7-methylenedioxy-N-methylisoquinoline（8）、N-methyl-6，7-dimethoxyisoquinoline（9）。对所有化合物进行乙酰胆碱酯酶抑制活性筛选，结果显示化合物4表现出一定的乙酰胆碱酯酶抑制作用，进一步通过分子对接分析其结合模式。研究结果为阐明娇嫩黄堇的药用物质基础提供了重要依据。

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