Article(id=1276976031797997986, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276975955985961244, articleNumber=null, orderNo=null, doi=10.19540/j.cnki.cjcmm.20251009.203, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1745596800000, receivedDateStr=2025-04-26, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1782384411048, onlineDateStr=2026-06-25, pubDate=1767196800000, pubDateStr=2026-01-01, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1782384411048, onlineIssueDateStr=2026-06-25, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1782384411048, creator=13701087609, updateTime=1782384411048, updator=13701087609, issue=Issue{id=1276975955985961244, tenantId=1146029695717560320, journalId=1276577828834349082, year='2026', volume='51', issue='1', pageStart='1', pageEnd='300', issueExtLink='null', onlineDate='null', pubDate='1767196800000', pubDateStr='2026-01-01', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=-1, specialIssue=null, createTime=1782384392973, creator='13701087609', updateTime=1782384484405, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1276976339546673871, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276975955985961244, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1276976339546673872, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276975955985961244, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=121, endPage=132, ext={EN=ArticleExt(id=1276976032246788516, articleId=1276976031797997986, tenantId=1146029695717560320, journalId=1276577828834349082, language=EN, title=A new eudesmane-type sesquiterpenoid from Sanguisorba officinalis, columnId=null, journalTitle=Chinese Journal of Traditional Chinese Medicine, columnName=null, runingTitle=null, highlight=null, articleAbstract=

The chemical constituents from Sanguisorba officinalis were isolated and purified through macroporous resin, silica gel, polyamide, ODS, Sephadex LH-20 column chromatography, and preparative HPLC. Their structures were determined by extensive analysis of data from MS, NMR, OR, and calculated NMR and ECD. Twenty-six compounds (1-26) were isolated from the 95% ethanol extract of S. officinalis and identified as (1S, 4S, 5R, 7S, 10R, 11R)-1α, 11, 12-trihydroxy-eudesmane (1), vomifolilol (2), (3S, 5R, 6R, 7E)-3, 5, 6-trihydroxy-7-megastigmen-9-one (3), threo-1, 2-bis- (4-hydroxy-3-methoxyphenyl)-propane-1, 3-diol (4), erythro-1, 2-bis- (4-hydroxy-3-methoxyphenyl)-propane-1, 3-diol (5), phenylformic acid (6), vanillic acid (7), veratric acid (8), 3, 4-dimethoxy-5-hydroxybenzoic acid (9), 4- (1-hydroxy-1-methylethyl)-benzoic acid (10), p-hydrocoumaric acid (11), 4-hydroxyphenethyl alcohol (12), ω-hydroxypropioguaiacone (13), cytosporone V (14), indazole (15), 1H-indole-3-carboxylic acid (16), 7, 8-dimethyl-iso-alloxazine (17), (-)-jasmonic acid (18), 12-hydroxyjasmonic acid (19), (-)-methyl 12-hydroxyjasmonate (20), 5-hydroxyhexan-4-olide (21), (8R^*, 9R^*, 10S^*, 6Z)-trihydroxyoctadec-6-enoic acid (22), (9S, 10R, 11E, 13R)-9, 10, 13-trihydroxyoctadec-11-enoic acid (23), methyl (9S, 10R, 11E, 13R)-9, 10, 13-trihydroxyoctadec-11-enoate (24), pinellic acid (25), and (9E)-8, 11, 12-trihydroxyoctadecenoic acid methyl ester (26). Compound 1 was a new eudesmane-type sesquiterpenoid and named sanguisorbaol M. Compounds 3-5, 8, 10, 14-17, 19-23, 25, and 26 were isolated from Rosaceae for the first time. Compounds 2, 11, 12, 18, and 24 were firstly isolated from the genus Sanguisorba and compound 6 was isolated from S. officinalis for the first time. The inhibitory effects of the isolated compounds on melanin synthesis were evaluated via the 3-isobutyl-1-methylxanthine (IBMX)-induced B16F10 melanoma cell model. The results showed that compounds 1-3 at a concentration of 50 μmol·L^-1 had a significant anti-melanogenic activity.

, authors=null, authorsList=Long-long WU, Jia-rui WU, Liu-qiang ZHANG, Yi-ming LI, Rong-bin WANG, authorCompany=null, correspAuthors=Rong-bin WANG, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1276976033077260711, articleId=1276976031797997986, tenantId=1146029695717560320, journalId=1276577828834349082, language=CN, title=地榆中1个新的桉烷型倍半萜类化合物, columnId=1276976014295167305, journalTitle=中国中药杂志, columnName=化学, runingTitle=null, highlight=null, articleAbstract=

采用大孔树脂、硅胶、聚酰胺、ODS、Sephadex LH-20柱色谱以及半制备HPLC等色谱分离技术，结合MS、NMR、OR、计算NMR和ECD等现代波谱分析技术，从地榆95%乙醇提取物中分离鉴定了26个化合物，分别为（1S，4S，5R，7S，10R，11R）-1α，11，12-三羟基桉烷（1）、vomifolilol（2）、（3S，5R，6R，7E）-3，5，6-trihydroxy-7-megastigmen-9-one（3）、threo-1，2-bis-（4-hydroxy-3-methoxyphenyl）-propane-1，3-diol（4）、erythro-1，2-bis-（4-hydroxy-3-methoxyphenyl）-propane-1，3-diol（5）、苯甲酸（6）、香草酸（7）、veratric acid（8）、3，4-二甲氧基-5-羟基苯甲酸（9）、4-（1-羟基-1-甲基乙基）苯甲酸（10）、对羟基苯丙酸（11）、酪醇（12）、ω-hydroxypropioguaiacone（13）、cytosporone V（14）、indazole（15）、1H-indole-3-carboxylic acid（16）、7，8-二甲基异咯嗪（17）、（-）-jasmonic acid（18）、12-羟基茉莉酮酸（19）、（-）-methyl 12-hydroxyjasmonate（20）、5-羟基己酸-4-内酯（21）、（8R^*，9R^*，10S^*，6Z）-trihydroxyoctadec-6-enoic acid（22）、（9S，10R，11E，13R）-9，10，13-trihydroxyoctadec-11-enoic acid（23）、methyl（9S，10R，11E，13R）-9，10，13-trihydroxyoctadec-11-enoate（24）、pinellic acid（25）、（9E）-8，11，12-trihydroxyoctadecenoic acid methyl ester（26）。其中化合物1为新化合物，命名为sanguisorbaol M；化合物6为首次从地榆中分离得到；化合物2、11、12、18、24为首次从地榆属中分离得到；化合物3～5、8、10、14～17、19～23、25、26为首次从蔷薇科中分离得到。采用3-异丁基-1-甲基黄嘌呤（IBMX）诱导的B16F10黑色素瘤细胞体外模型评价所分离化合物对黑色素合成的抑制活性，化合物1～3在50 μmol·L^-1浓度下均具有显著的抗黑色素生成活性。

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吴龙龙，讲师，研究方向为中药药效物质基础，E-mail: longlongwuamour@163.com

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吴龙龙，讲师，研究方向为中药药效物质基础，E-mail: longlongwuamour@163.com

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