Article(id=1276976181564019336, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276976057215488893, articleNumber=null, orderNo=null, doi=10.19540/j.cnki.cjcmm.20251009.202, pmid=null, cstr=null, oa=null, hot=null, price=null, onlineType=0, articleFormat=0, articleType=null, articleTypeStr=null, receivedDate=1748275200000, receivedDateStr=2025-05-27, revisedDate=null, revisedDateStr=null, acceptedDate=null, acceptedDateStr=null, onlineDate=1782384446754, onlineDateStr=2026-06-25, pubDate=1768406400000, pubDateStr=2026-01-15, doiRegisterDate=null, doiRegisterDateStr=null, onlineIssueDate=1782384446754, onlineIssueDateStr=2026-06-25, onlineJustAcceptDate=null, onlineJustAcceptDateStr=null, onlineFirstDate=null, onlineFirstDateStr=null, sourceXml=null, magXml=null, createTime=1782384446754, creator=13701087609, updateTime=1782384446754, updator=13701087609, issue=Issue{id=1276976057215488893, tenantId=1146029695717560320, journalId=1276577828834349082, year='2026', volume='51', issue='2', pageStart='301', pageEnd='600', issueExtLink='null', onlineDate='null', pubDate='1768406400000', pubDateStr='2026-01-15', beforeIssueId=null, nextIssueId=null, price=null, status=1, issueComplete=1, articleOrder=1, issueType=1, specialIssue=null, createTime=1782384417107, creator='13701087609', updateTime=1782384524478, updator='13701087609', preIssue=null, nextIssue=null, articleTotal=null, ext={EN=IssueExt(id=1276976507658563977, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276976057215488893, language=EN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=), CN=IssueExt(id=1276976507658563978, tenantId=1146029695717560320, journalId=1276577828834349082, issueId=1276976057215488893, language=CN, specialIssueTitle=, coverIllustrator=null, specialIssueEditor=, specialIssueAbout=)}, issueFiles=null, downloadFileDto=null}, startPage=444, endPage=449, ext={EN=ArticleExt(id=1276976181752763018, articleId=1276976181564019336, tenantId=1146029695717560320, journalId=1276577828834349082, language=EN, title=Secondary metabolites from Rhododendron molle endophyte Penicillium sp. RM and their inhibitory effects on tumor cell proliferation, columnId=null, journalTitle=Chinese Journal of Traditional Chinese Medicine, columnName=null, runingTitle=null, highlight=null, articleAbstract=

This study investigated the secondary metabolites of the endophytic fungus Penicillium sp. RM isolated from the toxic plant Rhododendron molle. Ten compounds were isolated and purified from the ethyl acetate extract of the fungal fermentation broth by silica gel column chromatography, gel column chromatography, and semi-preparative HPLC. The structures of these compounds were elucidated by comprehensive spectroscopic analyses, including NMR, MS, UV, IR, and CD. The identified compounds were as follows: penicidienone A (1), diversonol (2), alternariol (3), alternariol 9-methyl ether (4), methylated dechloromonilicin (5), norliquexantona (6), alternethanoxin A (7), α-diversonolic ester (8), (±) -asperlone A (9), and verruculotoxin (10). Compound 1 was identified as a new cyclopentenone derivative. Compound 9 showed inhibitory activity against the proliferation of HepG2 (IC₅₀=9.7 μmol·L^-1), HGC27 (IC₅₀ = 9.3 μmol·L^-1), and U251 (IC₅₀ = 8.4 μmol·L^-1) cell lines.

, authors=null, authorsList=Xue WANG, Lei ZHOU, Yi-hang HU, Yang LIU, Xue ZHANG, Yun-bao LIU, authorCompany=null, correspAuthors=Xue ZHANG, Yun-bao LIU, authorNote=null, correspAuthorsNote=null, copyrightStatement=null, copyrightOwner=null, extLink=null, articleAbsUrl=null, sourceXml=null, magXml=null, pdfUrl=null, pdf=null, pdfFileSize=null, pdfExtLink=null, richHtmlUrl=null, mobilePdfUrl=null, reviewReport=null, pdfFirstPage=null, abstractGraph=null, abstractGraphContent=null, abstractVideo=null, citation=null, cebUrl=null, magXmlContent=null, mapNumber=null, fund=null), CN=ArticleExt(id=1276976182017004172, articleId=1276976181564019336, tenantId=1146029695717560320, journalId=1276577828834349082, language=CN, title=羊踯躅内生真菌Penicillium sp. RM的次生代谢产物及其肿瘤细胞增殖抑制活性研究, columnId=1276976014295167305, journalTitle=中国中药杂志, columnName=化学, runingTitle=null, highlight=null, articleAbstract=

对羊踯躅内生真菌Penicillium sp. RM的次级代谢产物进行研究，采用硅胶柱色谱、凝胶柱色谱、半制备液相色谱等进行分离纯化，共从Penicillium sp. RM发酵物的乙酸乙酯部位中分离鉴定出10个化合物，利用NMR、MS、UV、IR、CD等现代波谱技术确定了化合物的结构，分别为penicidienone A（1）、diversonol（2）、alternariol（3）、alternariol 9-methyl ether（4）、methylated dechloromonilicin（5）、norliquexantona（6）、alternethanoxin A（7）、α-diversonolic ester（8）、（±）-asperlone A（9）、verruculotoxin （10），其中化合物1是1种新的环戊烯酮衍生物。肿瘤细胞增殖抑制活性筛选结果表明化合物9对HepG2、HGC27、U251细胞具有抑制作用，IC₅₀分别为9.7、9.3、8.4 μmol·L^-1。

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