To obtain the powder suppressant with greater inhibition effect, NaHCO3, Al(OH)3, K2CO3 and NH4H2PO4 were mixed by a compounding method, and a new composite powder was obtained. A visual spherical vessel was applied to study the effects of the composite powder with different mixing ratios on methane explosion overpressure, flame propagation and free radical production. The results indicate that as the mass proportion of NaHCO3, Al(OH)3, K2CO3 and NH4H2PO4 is 1∶1∶2∶1, the inhibition effect of composite powder is significantly greater than that of the single powder. The synergistic mechanisms of the composite powder are as follows: Before 250 ℃, the composite powder undergoes a metathesis reaction, a large number of gases such as H2O, CO2 and NH3 are released. In the early stage of methane explosion, the energy is absorbed and methane is diluted by the gases, so the rapid flame propagation is inhibited. NH4H2PO4 plays a role in absorbing C-containing free radicals during methane combustion. This effect is enhanced when powder is mixed, leading to a further inhibition for methane combustion reaction.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |