To address the short‑term overtemperature issues during service of ultra‑high‑pressure polyethylene tubular reactors,optical microscopy (OM),scanning electron microscopy (SEM),energy‑dispersive X‑ray spectroscopy (EDS),Vickers hardness testing,and nanoindentation were employed to systematically investigate the effects of overtemperature temperature,duration,and overtemperature cycles on the microstructure and mechanical properties of key material 30CrNiMo8 steel.Results show that during overtemperature for approximately 30 s,the primary effect on 30CrNiMo8 steel shifts from phase transformation to changes in grain size and morphology,manifested as enhanced brittleness and reduced hardness.When overtemperature exceeds the complete austenitization temperature to 860 ℃,material hardness first sharply increases then decreases due to massive martensite precipitation,carbide formation,and segregation of C,Cr,and Mo elements at grain boundaries.After 6 overtemperature cycles,martensite laths significantly widen with altered bundle orientations,causing grain structure coarsening and mechanical property degradation.This study provides data support and design references for safe operation of ultra‑high‑pressure polyethylene tubular reactors.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |