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Research of Thermal Catalytic Decomposition of 13CF4 to 13CO2
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Jiaqiang LUO, Meifang LI, Jianping YANG, Xiaoguang WANG
Uranium Mining and Metallurgy | 2025, 44(2) : 84 - 88
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Uranium Mining and Metallurgy | 2025, 44(2): 84-88
MINING AND HYDROMETALLURGY
Research of Thermal Catalytic Decomposition of 13CF4 to 13CO2
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Jiaqiang LUO, Meifang LI, Jianping YANG, Xiaoguang WANG
Affiliations
  • Cangzhou Nuclear Fuel Co., Ltd., CNNC, Cangzhou 061000, China
Published: 2025-05-20 doi: 10.13426/j.cnki.yky.2024.08.07
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In order to solve the problems of microwave plasma decomposition of 13CF4, such as complex operation process, harsh decomposition conditions and easy corrosion of reaction tubes,the thermal catalytic decomposition of 13CF4 to produce 13CO2 was studied. Under the condition of anhydrous and high temperature, 13CF4 was decomposed into 13CO2 by gas-solid reaction between 13CF4 and solid defluorination agent, using γ-Al2O3 as solid defluorination agent, meanwhile, the metal oxide in the defluorination agent is converted into metal fluoride. The results show that when the flow rate of reaction gas is 120 mL/min, the loading amount of catalyst is more than 60 g, the content of O2 in feed gas mixture is more than 50%, and the temperature of high temperature tubular furnace is 900℃, the conversion of γ-Al2${{\mathrm{O}}_{3}}_{}$ catalyst to 13CF4 gas is over 90%, which has good catalytic decomposition performance and can realize continuous catalysis and decomposition. The catalytic decomposition process has the advantages of simple process, convenient operation and very high carbon yield, and can be used in industrial production.

γ-Al2O3  /  catalytic  /  decomposition  /  13CF4  /  13CO2
Jiaqiang LUO, Meifang LI, Jianping YANG, Xiaoguang WANG. Research of Thermal Catalytic Decomposition of 13CF4 to 13CO2[J]. Uranium Mining and Metallurgy, 2025 , 44 (2) : 84 -88 . DOI: 10.13426/j.cnki.yky.2024.08.07
Year 2025 volume 44 Issue 2
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doi: 10.13426/j.cnki.yky.2024.08.07
  • Receive Date:2024-08-20
  • Online Date:2025-07-04
  • Published:2025-05-20
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  • Received:2024-08-20
Affiliations
    Cangzhou Nuclear Fuel Co., Ltd., CNNC, Cangzhou 061000, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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