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Adsorption Performance of Salicylic Acid Chelating Resin for Uranium
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Fengju WANG, Shusen CHEN, Yan SONG, Ziming LI, Haotian WU, Hao LI, He LI
Uranium Mining and Metallurgy | 2024, 43(3) : 40 - 44
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Uranium Mining and Metallurgy | 2024, 43(3): 40-44
MINING AND HYDROMETALLURGY
Adsorption Performance of Salicylic Acid Chelating Resin for Uranium
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Fengju WANG, Shusen CHEN, Yan SONG, Ziming LI, Haotian WU, Hao LI, He LI
Affiliations
  • Beijing Research Institute of Chemical Engineering and Metallurgy, CNNC, Beijing 101149, China
Published: 2024-08-20 doi: 10.13426/j.cnki.yky.2024.01.02
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For the salicylic acid chelating resin, the specific surface area and pore size were determined using low temperature nitrogen adsorption-desorption method; and its thermodynamic stability was examined. The effects of solution pH and ρ(Cl-) on its uranium adsorption performance were studied, and its adsorption isotherms, adsorption kinetics, and desorption performance were also investigated. The results show that the specific surface area of salicylic acid chelating resin is 32.34 m2/g, and the pore size is 32.08 nm, The salicylic acid chelated resin has good thermal stability when the temperature is below 180 ℃. When the pH is in the range of 7~9, the resin has good adsorption performance, and the uranium adsorption capacity can reach 14.1 mg/g dry resin. The presence of Cl- can reduce the adsorption capacity for uranium. When the ρ(Cl-) is 3.0 g/L, the uranium adsorption capacity decrease by about 9.2%. When the equilibrium ρ(U) in solution is 400 mg/L, the uranium adsorption capacity of the resin reach its maximum, at 153 mg/g dry resin. After 20 h adsorption, the adsorption process reach equilibrium. Both acidic and alkaline desorption agents show good desorption performance for resins, with desorption rates both above 94%. For the real uranium leaching solution with ρ(U) of 21.2 mg/L and ρ(Cl-) of 3.36 g/L, the uranium adsorption capacity of the salicylic acid chelating resin can reach 14.7 mg/g dry resin after 24 h adsorption, indicating good uranium adsorption performance.

salicylic acid  /  chelate  /  resin  /  uranium  /  adsorption  /  leaching solution
Fengju WANG, Shusen CHEN, Yan SONG, Ziming LI, Haotian WU, Hao LI, He LI. Adsorption Performance of Salicylic Acid Chelating Resin for Uranium[J]. Uranium Mining and Metallurgy, 2024 , 43 (3) : 40 -44 . DOI: 10.13426/j.cnki.yky.2024.01.02
Year 2024 volume 43 Issue 3
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doi: 10.13426/j.cnki.yky.2024.01.02
  • Receive Date:2024-01-09
  • Online Date:2025-07-04
  • Published:2024-08-20
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  • Received:2024-01-09
Affiliations
    Beijing Research Institute of Chemical Engineering and Metallurgy, CNNC, Beijing 101149, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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