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Simultaneous Determination of As and Hg in Uranium Ore by Hydride Generation Atomic Fluorescence Spectrometer
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Yuanyuan DING, Yang LU, Kaihua DU, Wuran LIU, Guolong GUO
Uranium Mining and Metallurgy | 2024, 43(3) : 50 - 55
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Uranium Mining and Metallurgy | 2024, 43(3): 50-55
MINING AND HYDROMETALLURGY
Simultaneous Determination of As and Hg in Uranium Ore by Hydride Generation Atomic Fluorescence Spectrometer
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Yuanyuan DING, Yang LU, Kaihua DU, Wuran LIU, Guolong GUO
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  • Beijing Research Institute of Chemical Engineering and Metallurgy, CNNC, Beijing 101149, China
Published: 2024-08-20 doi: 10.13426/j.cnki.yky.2024.03.06
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A method for simultaneous determination of As and Hg in uranium ore by hydride generation atomic fluorescence spectrometer was established, and the effects of digestion temperature, digestion time, medium system, KBH4 concentration, and uranium content on the detection results were investigated. The results show that the optimal conditions for this method are to dissolve uranium ore with (1+1) aqua regia for 60 minutes at 125 ℃, (5+95)HCl as the medium and 2.0% KBH4 solution as the reducing agent. The detection limits of this method are 0.006 μg/g (for As) and 0.001 μg/g (for Hg), with relative standard deviations of 2.46% (for As) and 4.22% (for Hg), and recovery rates of 98%~103%(for As) and 97%~106% (for Hg). This method has high accuracy and precision, and can meet the requirements for the determination of As and Hg in uranium ore.

hydride generation atomic florescence spectrometer  /  uranium ore  /  As  /  Hg  /  recovery
Yuanyuan DING, Yang LU, Kaihua DU, Wuran LIU, Guolong GUO. Simultaneous Determination of As and Hg in Uranium Ore by Hydride Generation Atomic Fluorescence Spectrometer[J]. Uranium Mining and Metallurgy, 2024 , 43 (3) : 50 -55 . DOI: 10.13426/j.cnki.yky.2024.03.06
Year 2024 volume 43 Issue 3
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doi: 10.13426/j.cnki.yky.2024.03.06
  • Receive Date:2024-03-26
  • Online Date:2025-07-04
  • Published:2024-08-20
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  • Received:2024-03-26
Affiliations
    Beijing Research Institute of Chemical Engineering and Metallurgy, CNNC, Beijing 101149, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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