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Analysis of Influencing Factors on Determination of Total Rare Earth in RECl3(L) by EDTA Method
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Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU
Rare Earth Steel | 2017, 43(6) : 64 - 68
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Rare Earth Steel | 2017, 43(6): 64-68
• Quality of Variety and Experiment and Research •
Analysis of Influencing Factors on Determination of Total Rare Earth in RECl3(L) by EDTA Method
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Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU
Affiliations
  • Smelting Branch Co. of Hi-tech Co. Ltd. of China Northern Rare Earth (Group) Corp. (Huamei Co.), Baotou 014010, Nei Monggol, China
Published: 2017-12-25 doi: 10.13647/j.cnki.btgkj.2017.06.022
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The total amount of rare earth in mixed rare earth chloride solution [RECl3(L)] is determined by EDTA titration and the effects of glass metering instruments, analytical reagents, sample homogeneity and non-rare earth metal ions on the measurement results are studied. The results show that: Glass metering instruments have the greater impact on the measurement results, especially the error accumulation effect of metering instruments, and errors of total rare earth correction (within the maximum allowable calibration error) can reach 3.66 g/L; the effect of aluminum and iron ions on the measurement results can be eliminated by adding masking agents; the zinc ion concentration is small and the effect on the results can be negligible. In the daily analysis process, pay attention to analyze the quality and correct use of reagents, ensuring the homogeneity of samples, reducing the analysis error, and improve the accuracy of analysis results.

mixed rare earth chloride solution  /  EDTA titration  /  metering instruments  /  non-rare earth metal ions  /  error accumulation effect
都业俭, 张桂梅, 薛建萍, 陈强, 王鸿宇, 郭建鹏, 孙二凤, 吴粉连. EDTA法测定RECl3(L)稀土总量影响因素分析. 包钢科技, 2017 , 43 (6) : 64 -68 . DOI: 10.13647/j.cnki.btgkj.2017.06.022
Ye-jian DU, Gui-mei ZHANG, Jian-ping XUE, Qiang CHEN, Hong-yu WANG, Jian-peng GUO, Er-feng SUN, Fen-lian WU. Analysis of Influencing Factors on Determination of Total Rare Earth in RECl3(L) by EDTA Method[J]. Science & Technology of Baotou Steel, 2017 , 43 (6) : 64 -68 . DOI: 10.13647/j.cnki.btgkj.2017.06.022
Year 2017 volume 43 Issue 6
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doi: 10.13647/j.cnki.btgkj.2017.06.022
  • Receive Date:2016-12-28
  • Online Date:2026-10-20
  • Published:2017-12-25
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  • Received:2016-12-28
Affiliations
    Smelting Branch Co. of Hi-tech Co. Ltd. of China Northern Rare Earth (Group) Corp. (Huamei Co.), Baotou 014010, Nei Monggol, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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