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Optimization of Mix Proportion and Performance Investigation of Solid-Waste-Based Cementitious Filling Materials
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Shaoning Yin, Peng Yuan, Dong Pan, Kun Wang, Xiang Meng, Jiawei Wu
Copper Engineering | 2026, (4) : 87 - 93
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Copper Engineering | 2026, (4): 87-93
Special Topic: Utilization of Mining and Metallurgical Solid Waste and Pollution Control
Optimization of Mix Proportion and Performance Investigation of Solid-Waste-Based Cementitious Filling Materials
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Shaoning Yin, Peng Yuan, Dong Pan, Kun Wang, Xiang Meng, Jiawei Wu
Affiliations
  • Institute of Technical Information for Building Materials Industry,Beijing 100024,China
Published: 2026-08-28 doi: 10.3969/j.issn.1009-3842.2026.04.011
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To address issues of high cost of traditional cement-based filling materials and poor bonding of ultra-fine tailings as a component, a solid-waste-based cementitious material was developed for the backfill of a molybdenum mine in Shaanxi Province. Steel slag, slag, and desulfurization gypsum were used as main raw materials, formulated with a performance modifier. The formulation of the solid-waste-based cementitious material was studied by varying the content and fineness of slag powder. The optimal formulation was selected to investigate application performance of backfill bodies and micromorphology of hydration products of the cementitious material. Results showed that the optimal formula of the solid-waste-based cementitious filling material was 60% slag powder (407 m2/kg), 20% steel slag powder, 20% desulfurization gypsum, and 0.6% performance regulator. Under this ratio, compressive strength of backfill bodies at all curing ages was superior to that of P·O 42.5 cement, with 28-day compressive strength reaching up to twice that of the cement group. Moreover, when cement-sand ratios were 1∶7, 1∶15, and 1∶16, respectively, strength requirements of different backfill zones were satisfied. Meanwhile, the material exhibited excellent fluidity and volume stability. Leaching toxicity indexes of all backfill bodies were lower than the limits specified in GB 8978—1996, indicating favorable environmental safety. Main hydration products were acicular-rod ettringite and fibrous gel-like C-S-H gel, which were interwoven to form a dense structure. The solid-waste-based cementitious filling material developed in this study had potentials of realizing resource utilization of solid waste and reducing backfill costs, providing technical support for green and efficient backfill of mines.

solid-waste-based cementitious backfill material  /  molybdenum mine tailings  /  mechanical property  /  application performance  /  microstructure morphology
Shaoning Yin, Peng Yuan, Dong Pan, Kun Wang, Xiang Meng, Jiawei Wu. Optimization of Mix Proportion and Performance Investigation of Solid-Waste-Based Cementitious Filling Materials[J]. Copper Engineering, 2026 , (4) : 87 -93 . DOI: 10.3969/j.issn.1009-3842.2026.04.011
Year 2026 volume Issue 4
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doi: 10.3969/j.issn.1009-3842.2026.04.011
  • Receive Date:2025-12-17
  • Online Date:2026-09-08
  • Published:2026-08-28
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  • Received:2025-12-17
  • Revised:2026-03-27
Affiliations
    Institute of Technical Information for Building Materials Industry,Beijing 100024,China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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