A P204-TOPO-sulfonated kerosene synergistic extraction-Fe(Ⅱ) reduction stripping system was constructed. The effects of extraction reaction time, phosphoric acid concentration, extraction temperature, amount of iron powder and stripping temperature were investigated, and the optimal process conditions were determined. The results show that the extraction-stripping of uranium conforms to the law of diffusion control-in-phase reaction. The apparent activation energy of the extraction reaction is 34.76 kJ/mol, and that of the stripping reaction is 40.289 kJ/mol. The system is controlled by both mass transfer and chemical reaction. The optimal extraction conditions are room temperature, extraction time of 6 min, phosphoric acid concentration of 3.5 mol/L, and VO/VA=1/5. The optimal stripping conditions are temperature of 323.15 K, stripping time of 10 min, phosphoric acid concentration of 5 mol/L, reduced iron powder amount of 10 times the theoretical amount, and VO/VA=5/1. Under the optimal conditions, the uranium extraction rate is 96% and the stripping rate is 81.3%.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |