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Discussion on Variation Characteristics of Vanadium Element Valence State During Roasting Process of Vanadium Slag
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Jian GAO1, 2, 3, Wei WU1, 2, 3, Yuyan SHA4, Xiang ZHONG1, 2, 3, Zhixin SHI1, 2, 3
Hydrometallurgy of China | 2024, 43(2) : 147 - 152
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Hydrometallurgy of China | 2024, 43(2): 147-152
Experiment Research
Discussion on Variation Characteristics of Vanadium Element Valence State During Roasting Process of Vanadium Slag
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Jian GAO1, 2, 3, Wei WU1, 2, 3, Yuyan SHA4, Xiang ZHONG1, 2, 3, Zhixin SHI1, 2, 3
Affiliations
  • 1 State Key Laboratory of Vanadium and Titanium, Resources Comprehensive Utilization, Panzhihua 617000, China
  • 2 Pangang Group Research Institute Co., Ltd., Panzhihua 617000, China
  • 3 Sichuan Panyan Testing Technology Co., Ltd., Panzhihua 617000, China
  • 4 Panzhihua Steel & Vanadium Co., Ltd., Pangang Group, Panzhihua 617000, China
Published: 2024-04-20 doi: 10.13355/j.cnki.sfyj.2024.02.006
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The mineral composition and valence state composition of vanadium clinker in vanadium slag and salt-free roasting stage at different temperature nodes were studied by photoelectron spectroscopy and mineral analyzer. The results show that the contents of vanadium spinel, ferroolivine and calciferite decrease with the increase of roasting temperature, while the contents of iron oxide, ferrotitanite and manganese vanadate increase with the increase of roasting temperature. With the increase of roasting temperature, the oxidation of vanadium slag from V3+ to V4+ is gradually transformed into the internal oxidation of V3+ to V4+ and V4+ to V5+. The valence state of vanadium in vanadium spinel is V3+ and the valence state of vanadium in oxidation state is V4+. The mineral analysis results of vanadium slag and clinker are in good agreement with the valence analysis results of vanadium element.

vanadium slag  /  salt-free roasting  /  vanadium element  /  valence state  /  variation  /  characteristic
Jian GAO, Wei WU, Yuyan SHA, Xiang ZHONG, Zhixin SHI. Discussion on Variation Characteristics of Vanadium Element Valence State During Roasting Process of Vanadium Slag[J]. Hydrometallurgy of China, 2024 , 43 (2) : 147 -152 . DOI: 10.13355/j.cnki.sfyj.2024.02.006
Year 2024 volume 43 Issue 2
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doi: 10.13355/j.cnki.sfyj.2024.02.006
  • Receive Date:2023-11-07
  • Online Date:2025-09-10
  • Published:2024-04-20
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  • Received:2023-11-07
Affiliations
    1 State Key Laboratory of Vanadium and Titanium, Resources Comprehensive Utilization, Panzhihua 617000, China
    2 Pangang Group Research Institute Co., Ltd., Panzhihua 617000, China
    3 Sichuan Panyan Testing Technology Co., Ltd., Panzhihua 617000, China
    4 Panzhihua Steel & Vanadium Co., Ltd., Pangang Group, Panzhihua 617000, China
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https://castjournals.cast.org.cn/joweb/sfyj/EN/10.13355/j.cnki.sfyj.2024.02.006
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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