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Multistage Leaching Kinetics of Chromite in HCl-Na2CrO4 System
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Chengzong JIAN, Yijuan TIAN, Ziwen JIANG, Chunyu YAN, Xuejun QUAN, Gang LI
Hydrometallurgy of China | 2024, 43(4) : 407 - 419
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Hydrometallurgy of China | 2024, 43(4): 407-419
Experiment Research
Multistage Leaching Kinetics of Chromite in HCl-Na2CrO4 System
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Chengzong JIAN, Yijuan TIAN, Ziwen JIANG, Chunyu YAN, Xuejun QUAN, Gang LI
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  • Institute of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400054, China
Published: 2024-08-20 doi: 10.13355/j.cnki.sfyj.2024.04.009
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The multi-stage leaching of chromite in HCl-Na2CrO4 system has been studied, and the leaching kinetics of main metal elements in chromite has been discussed. The results show that under the optimal conditions of particle size of 45~75 μm, oxidizing agent Na2CrO4 dosage of 0.6 times of theoretical dosage, reaction time of 5 h, reaction temperature of 453.15 K, ball to material mass ratio of 1/1, stirring speed of 30 r/min, liquid volume to solid mass ratio of 4 mL/1 g, the three-stage cyclic leaching is carried out, the leaching rates of Cr, Fe, Al and Mg can reach 91.98%, 94.54%, 76.62% and 78.03%, respectively. The acid leaching reaction of chromite is controlled by interfacial chemical reaction. The apparent activation energies of Cr, Fe, Al and Mg are 45.80, 40.43, 42.08 and 43.54 kJ/mol, respectively. In the range of 373.15~473.15 K, and the leaching effect is good.

chromite  /  chromium residue  /  hydrochloric acid  /  Na2CrO4  /  leaching  /  multistage  /  kinetics
Chengzong JIAN, Yijuan TIAN, Ziwen JIANG, Chunyu YAN, Xuejun QUAN, Gang LI. Multistage Leaching Kinetics of Chromite in HCl-Na2CrO4 System[J]. Hydrometallurgy of China, 2024 , 43 (4) : 407 -419 . DOI: 10.13355/j.cnki.sfyj.2024.04.009
Year 2024 volume 43 Issue 4
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doi: 10.13355/j.cnki.sfyj.2024.04.009
  • Receive Date:2024-04-02
  • Online Date:2025-09-10
  • Published:2024-08-20
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  • Received:2024-04-02
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    Institute of Chemistry and Chemical Engineering, Chongqing University of Technology, Chongqing 400054, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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