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Research Progress on Preparation of Electronic Grade Phosphoric Acid by Removing Arsenic from Wet-process Phosphoric Acid
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Rui XIAO1, Tao LI2, Meijie REN1, 3, Yimin HUANG1, 3, Ping NING1, 3, Fansong LIU1, 3
Hydrometallurgy of China | 2024, 43(5) : 504 - 512
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Hydrometallurgy of China | 2024, 43(5): 504-512
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Research Progress on Preparation of Electronic Grade Phosphoric Acid by Removing Arsenic from Wet-process Phosphoric Acid
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Rui XIAO1, Tao LI2, Meijie REN1, 3, Yimin HUANG1, 3, Ping NING1, 3, Fansong LIU1, 3
Affiliations
  • 1 School of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650000, China
  • 2 The Seventh Geological Brigdade of Jiangxi Bureau of Geology, Ganzhou 341000, China
  • 3 National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries, Kunming 650000, China
Published: 2024-10-20 doi: 10.13355/j.cnki.sfyj.2024.05.005
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The preparation of electronic grade phosphoric acid by deep removing arsenic from wet-process phosphoric acid is an important technical link to develop phosphorus chemical industry with high quality and promote the technological transformation of phosphorus chemical industry. Electronic grade phosphoric acid requires a mass fraction of arsenic less than 1×10-7 kg/kg, but because the physicochemical parameters of arsenic and phosphorus are similar, how to achieve the deep separation of arsenic from phosphoric acid has become the key to the preparation of electronic grade phosphoric acid. In this paper, the main international and domestic quality standards for electronic grade phosphoric acid products are systematically reviewed, and the harm of arsenic to electronic grade phosphoric acid etched microelectronic components is summarized. The research progress, advantages and disadvantages of chemical precipitation, crystallization, electrodeposition, electrodialysis and adsorption are summarized, and the development trend of electron grade phosphoric acid prepared by wet phosphoric acid is prospected.

wet-process phosphoric acid  /  arsenic  /  deep purification  /  electronic grade phosphoric acid  /  preparation  /  harm  /  research progress
Rui XIAO, Tao LI, Meijie REN, Yimin HUANG, Ping NING, Fansong LIU. Research Progress on Preparation of Electronic Grade Phosphoric Acid by Removing Arsenic from Wet-process Phosphoric Acid[J]. Hydrometallurgy of China, 2024 , 43 (5) : 504 -512 . DOI: 10.13355/j.cnki.sfyj.2024.05.005
Year 2024 volume 43 Issue 5
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doi: 10.13355/j.cnki.sfyj.2024.05.005
  • Receive Date:2024-06-21
  • Online Date:2025-09-10
  • Published:2024-10-20
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  • Received:2024-06-21
Affiliations
    1 School of Environmental Science and Engineering, Kunming University of Science and Technology, Kunming 650000, China
    2 The Seventh Geological Brigdade of Jiangxi Bureau of Geology, Ganzhou 341000, China
    3 National-Regional Engineering Center for Recovery of Waste Gases from Metallurgical and Chemical Industries, Kunming 650000, China
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https://castjournals.cast.org.cn/joweb/sfyj/EN/10.13355/j.cnki.sfyj.2024.05.005
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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