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Extraction Performance of Gallium with A New Alkyl Hydroxamic Acid DX201
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Wei ZHANG1, 2, Kehua ZHOU3, Yu SUN4, Wenxun LIAO1, Junfeng ZHANG1, Caigui WU1, 5
Hydrometallurgy of China | 2024, 43(6) : 658 - 664
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Hydrometallurgy of China | 2024, 43(6): 658-664
Experiment Research
Extraction Performance of Gallium with A New Alkyl Hydroxamic Acid DX201
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Wei ZHANG1, 2, Kehua ZHOU3, Yu SUN4, Wenxun LIAO1, Junfeng ZHANG1, Caigui WU1, 5
Affiliations
  • 1 Danxia Smelter, Shenzhen Zhongjin Lingnan Nonferrous Metals Co.,Ltd., Shaoguan 512325, China
  • 2 School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
  • 3 Shenzhen Zhongjin Lingnan Nonferrous Metals Co., Ltd., Shenzhen 518040, China
  • 4 School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
  • 5 Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
Published: 2024-12-20 doi: 10.13355/j.cnki.sfyj.2024.06.010
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The extraction performance of gallium in sulfuric acid solution with new alkyl hydroxamic acid DX201 and P204 was studied. The effects of extraction and stripping conditions on gallium extraction performance were investigated. The extraction and stripping isotherms were drawn. The results show that the single-stage extraction rate of gallium is 97.52% under the conditions of VO/VA=1/1, extraction temperature of 25 ℃ and extraction time of 15 min in sulfate solution with mass concentration of sulfuric acid of 20 g/L sulfate solution and organic phase composition of 10%DX201+15%P204+75%260#solvent oil. Using 2.5 mol/L dilute sulfuric acid solution to strip gallium from supported organic phase, the single stage stripping rate of gallium is 94.21% under the conditions of VO/VA=2/1, stripping temperature of 25 ℃ and stripping time of 2 min. The extraction rate of gallium in 3-stage countercurrent extraction is 99.64%, and the extraction performance is stable.

alkyl hydroxamic acid  /  P204  /  extraction  /  gallium  /  sulfuric acid system
Wei ZHANG, Kehua ZHOU, Yu SUN, Wenxun LIAO, Junfeng ZHANG, Caigui WU. Extraction Performance of Gallium with A New Alkyl Hydroxamic Acid DX201[J]. Hydrometallurgy of China, 2024 , 43 (6) : 658 -664 . DOI: 10.13355/j.cnki.sfyj.2024.06.010
Year 2024 volume 43 Issue 6
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doi: 10.13355/j.cnki.sfyj.2024.06.010
  • Receive Date:2024-04-25
  • Online Date:2025-09-10
  • Published:2024-12-20
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  • Received:2024-04-25
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Affiliations
    1 Danxia Smelter, Shenzhen Zhongjin Lingnan Nonferrous Metals Co.,Ltd., Shaoguan 512325, China
    2 School of Chemistry and Chemical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
    3 Shenzhen Zhongjin Lingnan Nonferrous Metals Co., Ltd., Shenzhen 518040, China
    4 School of Chemistry and Chemical Engineering, Wuhan University of Science and Technology, Wuhan 430081, China
    5 Faculty of Metallurgy and Energy Engineering, Kunming University of Science and Technology, Kunming 650093, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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