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Regulation and Mechanism of Biological Column Leaching of High-Sulfur and Low-Copper Ore by Limestone
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Jinyan LIU1, 2, Lan HUANG1, 2, Hongxu LI3, Yihao SUN1, 2, Weiran ZUO1, 2
Hydrometallurgy of China | 2025, 44(2) : 196 - 203
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Hydrometallurgy of China | 2025, 44(2): 196-203
Experiment Research
Regulation and Mechanism of Biological Column Leaching of High-Sulfur and Low-Copper Ore by Limestone
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Jinyan LIU1, 2, Lan HUANG1, 2, Hongxu LI3, Yihao SUN1, 2, Weiran ZUO1, 2
Affiliations
  • 1 Zijin School of Mining and Geology, Fuzhou University, Fuzhou 350108, China
  • 2 Fujian Key Laboratory of Green Extraction and High Value Utilization of New Energy Metals, Fuzhou 350108, China
  • 3 Zijin Mining Group Co., Ltd., Shanghang 364200, China
Published: 2025-04-28 doi: 10.13355/j.cnki.sfyj.2025.02.008
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To address the problem of excessive accumulation of iron acid in bio-heap leaching of high-sulfur and low-copper ore, the regulation and mechanism of leaching of high sulfur and low copper ores by limestone were studied by bio-column leaching method and MLA detection and analysis method. The results show that the pH and Eh of the leaching solution can be significantly regulated by adding limestone with mass fraction of 2% and particle size of -10 mm+5 mm to 1.4 t ore. After 7 months of biological column leaching, the copper leaching rate can reach 71.25%, which is 52.83% higher than that of the control group without adding limestone. The distribution size of pyrite in the leaching slag of limestone addition group increases, and no xanax passivation layer is found, and the dissociation degree of fine copper minerals is positively correlated with the leaching rate. The addition of limestone can effectively enhance the copper leaching efficiency in high-sulfur and low-copper ore and reduce the burden of acid-iron wastewater treatment, which is of great significance for the sustainable development of sulfide ore mining operations.

high-sulfur and low-copper ore  /  limestone  /  bio-column leaching  /  pH  /  Eh
Jinyan LIU, Lan HUANG, Hongxu LI, Yihao SUN, Weiran ZUO. Regulation and Mechanism of Biological Column Leaching of High-Sulfur and Low-Copper Ore by Limestone[J]. Hydrometallurgy of China, 2025 , 44 (2) : 196 -203 . DOI: 10.13355/j.cnki.sfyj.2025.02.008
Year 2025 volume 44 Issue 2
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Article Info
doi: 10.13355/j.cnki.sfyj.2025.02.008
  • Receive Date:2024-10-30
  • Online Date:2025-07-05
  • Published:2025-04-28
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  • Received:2024-10-30
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Affiliations
    1 Zijin School of Mining and Geology, Fuzhou University, Fuzhou 350108, China
    2 Fujian Key Laboratory of Green Extraction and High Value Utilization of New Energy Metals, Fuzhou 350108, China
    3 Zijin Mining Group Co., Ltd., Shanghang 364200, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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