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Synergistic Decomposition of Scheelite by HCl-H2SO4
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Guozuan XU1, Daibin ZHANG1, Chenglong HUANG1, Longhui ZHANG1, Degang LIU1, 2
Hydrometallurgy of China | 2025, 44(1) : 45 - 51
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Hydrometallurgy of China | 2025, 44(1): 45-51
Experiment Research
Synergistic Decomposition of Scheelite by HCl-H2SO4
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Guozuan XU1, Daibin ZHANG1, Chenglong HUANG1, Longhui ZHANG1, Degang LIU1, 2
Affiliations
  • 1 Chongyi Zhangyuan Tungsten Co., Ltd., Ganzhou, 341000, China
  • 2 School of Metallurgical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
Published: 2025-02-28 doi: 10.13355/j.cnki.sfyj.2025.01.007
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The synergistic decomposition of scheelite by HCl-H2SO4 was studied. The influence of various process parameters on the decomposition effect was investigated, and the kinetics of decomposition process was discussed. The results show that under the optimal conditions of hydrochloric acid concentration of 22%, liquid volume of concentrated sulfuric acid of 0.5%, liquid volume to solid mass ratio of 2.5∶1, decomposition temperature of 85 ℃, decomposition time of 2 h, stirring rate of 360 r/min, the decomposition rate of calcium tungstate in scheelite is 99.6%, and the decomposition rate is high. The process of HCl-H2SO4 synergistic decomposition of scheelite is controlled by chemical reaction and solid film mixing, and the apparent activation energy is 45.52 kJ/mol. The CaWO4 in scheelite can be efficiently converted into tungstic acid, thus effectively improving the tungsten extraction rate in scheelite.

scheelite  /  hydrochloric acid  /  sulfuric acid  /  synergistic decomposition  /  kinetics
Guozuan XU, Daibin ZHANG, Chenglong HUANG, Longhui ZHANG, Degang LIU. Synergistic Decomposition of Scheelite by HCl-H2SO4[J]. Hydrometallurgy of China, 2025 , 44 (1) : 45 -51 . DOI: 10.13355/j.cnki.sfyj.2025.01.007
Year 2025 volume 44 Issue 1
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doi: 10.13355/j.cnki.sfyj.2025.01.007
  • Receive Date:2024-08-04
  • Online Date:2025-07-05
  • Published:2025-02-28
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  • Received:2024-08-04
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    1 Chongyi Zhangyuan Tungsten Co., Ltd., Ganzhou, 341000, China
    2 School of Metallurgical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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