Extraction of aluminum from fly ash by ammonium sulfate roasting-leaching process was studied. The effects of roasting temperature, roasting time and the molar ratio of ammonium sulfate to Al2O3 in fly ash on the extraction of aluminum from fly ash were investigated. The interaction of various factors on the extraction rate of aluminum from fly ash was discussed by response surface method, and the optimum roasting parameters were determined. The phase and microstructure of fly ash raw materials and calcined products were characterized by X-ray diffractometer (XRD) and scanning electron microscope (SEM). The results show that the main product of fly ash activated by ammonium sulfate is NH4Al(SO4)2, and the surface of the roasted product is corroded. The optimum process parameters of activation roasting of fly ash are as follows:roasting temperature is 438 ℃, roasting time is 63.8 min, molar ratio of ammonium sulfate to Al2O3 in fly ash is 7.31. Under the optimum process conditions, the leaching rate of Al is 95.30%, and the leaching effect is better.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |