The lithium (Li) metal is one promising anode for next generation high-energy-density batteries, but the large stress fluctuation and the nonuniform Li deposition upon cycling result in a highly unstable interface of the Li anode. Herein, a simple yet facile engineering of the elastic interface on the Li metal anodes is designed by inserting a melamine sponge between Li and the separator. Driven by the good elasticity of the sponge, the modified Li anode maintains a Coulombic efficiency of 98.8% for 60 cycles and is cyclable at 10 mA cm^-2 for 250 cycles, both with a high capacity of 10 mA h cm^-2. We demonstrate that the sponge can be used to replace the conventional polypropylene as a porous yet elastic separator, showing superior cycling and rate performance as well. In addition to the efficiency of the elastic interface on the cycling stability, which is further confirmed by an in situ compression-electrochemistry measurement, the porous structure and polar groups of the sponge demonstrate an ability of regulating the transport of Li ions, leading to a uniform deposition of Li and the suppression of Li dendrites in cycling.

Vibration energy harvesters based on the resonance of the beam structure work effectively only when the operating frequency window of the beam resonance matches with the available vibration source. None of the resonating MEMS structures can operate with low frequency, low amplitude, and unpredictable ambient vibrations since the resonant frequency goes up very high as the structure gets smaller. Bistable buckled beam energy harvester is therefore developed for lowering the operating frequency window below 100Hz for the first time at the MEMS scale. This design does not rely on the resonance of the MEMS structure but operates with the large snapping motion of the beam at very low frequencies when input energy overcomes an energy threshold. A fully functional piezoelectric MEMS energy harvester is designed, monolithically fabricated, and tested. An electromechanical lumped parameter model is developed to analyze the nonlinear dynamics and to guide the design of the nonlinear oscillator based energy harvester. Multilayer beam structure with residual stress induced buckling is achieved through the progressive residual stress control of the deposition processes along the fabrication steps. Surface profile of the released device shows bistable buckling of 200\mu m which matches well with the amount of buckling designed. Dynamic testing demonstrates the energy harvester operates with 50% bandwidth under 70Hz at 0.5g input, operating conditions that have not been demonstrated by MEMS vibration energy harvesters before.

Multielectronic reaction electrode materials for high energy density lithium-ion batteries (LIBs) are severely hindered by their inherent sluggish kinetics and large volume variations, leading to rapid capacity fade. Here, a simple method is developed to construct low-carbon and nanosheathed ZnCo₂O₄ porous spheroids (ZCO@C-5). In this micro/nanostructure, an ultrathin amorphous carbon layer (~2 nm in thickness) is distributed all over the primary nanosized ZCO particles (~20 nm in diameter), which finally self-assembles into porous core (ZCO)-shell(carbon) micron spheroids. The nanoencapsulation and macro/mesoporous architecture can not only provide facile electrolyte penetration and rapid ion/electron transfer but also better alleviate volumetric expansion effect to avoid pulverization of ZCO@C-5 spheroids during repeat charge/discharge processes. As expected, the three-dimensional porous ZCO@C-5 composites exhibit high reversible capacity of 1240 mAh g⁻¹ cycle at 500 mA g⁻¹, as well as excellent long-term cycling stability and rate capability. The low-carbon and nanoencapsulation strategy in this study is simple and effective, exhibiting great potential for high-performance LIBs.

It is highly desired but challenging to achieve highly active single-atom Fe sites from iron-based metal-organic frameworks (MOFs) for efficient oxygen reduction reaction (ORR) due to the easy aggregation of iron species and formation of the inactive Fe-based particles during pyrolysis. Herein, a facile migration-prevention strategy is developed involving the incorporation of polyaniline (PANI) into the pores of iron porphyrinic-based MOF PCN-224(Fe) and followed by pyrolysis to obtain the single-atom Fe implanted N-doped porous carbons material PANI@PCN-224(Fe)-900. The introduced PANI inside the pores of PCN-224(Fe) not only served as protective fences to prevent the aggregation of the iron species during thermal annealing, but also acted as nitrogen sources to increase the nitrogen content and form Fe-{\mathrm{N}}_{\mathrm{x}}-C active sites. Compared with the pristine PCN-224(Fe) derived carbonization sample containing Fe-based particles, the carbonaceous material PANI@PCN-224(Fe)-900 without inactive Fe-based particles exhibited superb ORR electrocatalytic activity with a more positive half-wave potential, significantly improved stability in both alkaline media, and more challenging acidic condition. The migration-prevention strategy provides a new way to fabricate atomically dispersed metal active sites via pyrolysis approach for promoting catalysis.

Topological valley-contrasting physics has attracted great attention in exploring the use of the valley degree of freedom as a promising carrier of information. Recently, this concept has been extended to acoustic systems to obtain nonbackscattering sound propagations. However, previous demonstrations are limited by the cut-off frequency of 2D waveguides and lattice-scale size restrictions since the topological edge states originate from Bragg interference. Here we engineer topologically valley-projected edge states in the form of spoof surface acoustic waves that confine along the surface of a subwavelength honeycomb lattice composed of 330-mL soda cans. The inversion symmetry is broken through injecting a certain amount of water into one of the two cans in each unit cell, which gaps the Dirac cone and ultimately leads to the topological valley-Hall phase transition. Dual-frequency ranges of the valley-projected edge states below the sound line are observed, which originate from the first-order and second-order resonances, respectively. These results have the potential to enable promising routes to design integrated acoustic devices based on valley-contrasting physics.

Nucleotide excision repair (NER) is an essential DNA repair system distinguished from other such systems by its extraordinary versatility. NER removes a wide variety of structurally dissimilar lesions having only their bulkiness in common. NER can also repair several less bulky nucleobase lesions, such as 8-oxoguanine. Thus, how a single DNA repair system distinguishes such a diverse array of structurally divergent lesions from undamaged DNA has been one of the great unsolved mysteries in the field of genome maintenance. Here we employ a synthetic crystallography approach to obtain crystal structures of the pivotal NER enzyme UvrB in complex with duplex DNA, trapped at the stage of lesion-recognition. These structures coupled with biochemical studies suggest that UvrB integrates the ATPase-dependent helicase/translocase and lesion-recognition activities. Our work also conclusively establishes the identity of the lesion-containing strand and provides a compelling insight to how UvrB recognizes a diverse array of DNA lesions.

A simple model of charge transfer by loss-less quantum-mechanical tunneling between two solids is proposed. The model is applicable to electron transport and contact electrification between e.g. a metal and a dielectric solid. Based on a one-dimensional effective-mass Hamiltonian, the tunneling transmission coefficient of electrons through a barrier from one solid to another solid is calculated analytically. The transport rate (current) of electrons is found using the Tsu-Esaki equation and accounting for different Fermi functions of the two solids. We show that the tunneling dynamics is very sensitive to the vacuum potential versus the two solids conduction-band edges and the thickness of the vacuum gap. The relevant time constants for tunneling and contact electrification, relevant for triboelectricity, can vary over several orders of magnitude when the vacuum gap changes by one order of magnitude, say, \mathrm{1} Å to \mathrm{10} Å. Coulomb repulsion between electrons on the left and right material surfaces is accounted for in the tunneling dynamics.

Self-assembled DNA nanostructures hold great promise as nanoscale templates for organizing nanoparticles (NPs) with near-atomistic resolution. However, large-scale organization of NPs with high yield is highly desirable for nanoelectronics and nanophotonic applications. Here, we design five-strand DNA tiles that can readily self-assemble into well-organized micrometer-scale DNA nanostructures. By organizing gold nanoparticles (AuNPs) on these self-assembled DNA nanostructures, we realize the fabrication of one- and two-dimensional Au nanostructures in single steps. We further demonstrate the one-pot synthesis of Au metamaterials for highly amplified surface-enhanced Raman Scattering (SERS). This single-step and high-yield strategy thus holds great potential for fabricating plasmonic metamaterials.

The well-known small-world network model was established by randomly rewiring edges, aiming to enhance the synchronizability of an undirected nearest-neighbor regular network. This paper demonstrates via extensive numerical simulations that randomly redirecting edges could enhance the robustness of the network controllability for directed snapback networks against both random and intentional node-removal and edge-removal attacks.

Material interfaces permit electron transfer that modulates the electronic structure and surface properties of catalysts, leading to radically enhanced rates for many important reactions. Unlike conventional thoughts, the nanoscale interfacial interactions have been recently envisioned to be able to affect the reactivity of catalysts far from the interface. However, demonstration of such unlocalized alterations in existing interfacial materials is rare, impeding the development of new catalysts. We report the observation of unprecedented long-range activation of polydymite Ni₃S₄ nanorods through the interfacial interaction created by {\mathrm{P}\mathrm{d}\mathrm{S}}_{\mathrm{x}} nanodots (dot-on-rod structure) for high-performance water catalytic electroreduction. Experimental results show that this local interaction can activate Ni₃S₄ rods with length even up to 25 nanometers due to the tailored surface electronic structure. We anticipate that the long-range effect described here may be also applicable to other interfacial material systems, which will aid the development of newly advanced catalysts for modern energy devices.