The study established an ultra-performance liquid chromatography-tandem mass spectrometry technique for the simultaneous determination of six methoxyacrylate fungicides to clarify the possible cumulative dietary intake risk of methoxyacrylate fungicides in fresh mango. The Monte Carlo simulation and relative potency factor methods were employed to assess the cumulative risk of acute and chronic exposure to strobilurin intake from mango consumption in the targeted populations. In 126 mango samples from Hainan, Guangxi and Yunnan, 3 of 6 methoxyacrylate fungicide were detected. The detection rate of pyraclostrobin, azoxystrobinthe and kresoxim-methyl was 31%, 37% and 14% respectively. Picoxystrobin, trifloxystrobin and fluoxastrobin in mango samples were not detected. The ratio of methoxyacrylate fungicide found in a mango sample was 22%. The ratio of 2 and 3 kinds methoxyacrylate fungicides found in a mango sample was 22% and 5%. The most common co-occurrence of methoxyacrylate fungicides was pyraclostrobin and azoxystrobin. The results of dietary risk assessment showed that the risk of residual methoxyacrylate fungicides in mango ranged between 0.1% and 10.2% for acute dietary exposure and between 0.1% and 1.2% for chronic dietary exposure. The exposure was far below the thresholds of dietary risk. The study showed that the cumulative chronic and acute dietary exposure risk of methoxyacrylate fungicide residues in mango are within an acceptable range and do not pose an unacceptable risk to the health of the targeted population.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |