To study the differences in the physical and chemical properties of biochar obtained from three legumes at different temperatures, and to determine the appropriate temperature range for legume biochar. Using leguminous plant peanut straw, soybean straw and stylofoam as raw materials, peanut straw biochar (Pe), soybean straw biochar (Be) and stylofoam biochar (St) were prepared at 300 ℃, 500 ℃ and 700 ℃. A Fourier infrared spectrometer was used to qualitatively analyze the functional groups on the surface of the biochar, and the surface morphology of the biochar was observed with a scanning electron microscope, and the physical and chemical properties, such as pH, C and N content, were measured. The results showed that the carbon content of biochar prepared from three kinds of raw materials increased with the increase of pyrolysis temperature at 300 ℃ to 500 ℃, and was basically stable after 500 ℃; the nitrogen content and yield of biochar decreased with the increase of temperature. Among the biomass charcoal prepared from the three materials, Be has the highest carbon content and C/N, and N content and yield are the lowest. The ash content, ash alkalinity and pH of biochar all increase with the increase of pyrolysis temperature. The same pyrolysis ash alkalinity and pH of biochar all increase with the increase of pyrolysis temperature. The same pyrolysis temperature and different materials are all expressed as Be>St>Pe. Both the pore size and specific surface area of biochar increase with increasing temperature. The three raw materials of biochar form more stable aromatic compounds with increasing temperature, and the structure is mainly C=O and C=C. In this study, the suitable pyrolysis temperature of legume biochar is 500 ℃, and the temperature rises again, which has little effect on the physical and chemical properties of biochar. In summary, the soybean biochar produced by cracking at 500 ℃ is more used in farmland soil improvement, and can also try soil remediation, carbon sequestration and emission reduction applications.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |