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Preparation and Characterization of Tapioca Starch Sodium Octenyl Succinate with Non-alcohol Esterification
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Yuanyuan GAO1, Ruyi LI1, *, Yingying LI1, Wei ZHOU1, Xiaobing HUANG1, Shaodan PENG1, Jihua LI1, 2
Chinese Journal of Tropical Crops | 2024, 45(12) : 2719 - 2727
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Chinese Journal of Tropical Crops | 2024, 45(12): 2719-2727
Post-harvest Treatment & Quality Safety
Preparation and Characterization of Tapioca Starch Sodium Octenyl Succinate with Non-alcohol Esterification
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Yuanyuan GAO1, Ruyi LI1, *, Yingying LI1, Wei ZHOU1, Xiaobing HUANG1, Shaodan PENG1, Jihua LI1, 2
Affiliations
  • 1.Agricultural Products Processing Research Institute / Key Laboratory of Tropical Crop Products Processing, Ministry of Agriculture and Rural Affairs, Zhanjiang, Guangdong 524001, China
  • 2.Chinese Academy of Tropical Agricultural Sciences, Haikou, Hainan 524091, China
Published: 2024-12-25 doi: 10.3969/j.issn.1000-2561.2024.12.024
Outline
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Starch sodium octenyl succinate is a food additive produced by the process of esterification using starch and octenyl succinic anhydride. In this study, the tapioca starch sodium octenyl succinate was prepared and characterized with non-alcohol esterification by substituting the organic reagent-dispersed OSA with the OSA emulsification technique. The results showed that OSA emulsion prepared with soybean phospholipid (SP) as an emulsifier had good stability and dispersibility. The octenyl succinic acid group content, degree of substitution, and substitution efficiency of 1.00% SP-SSOS made using OSA emulsions with 1.00% SP emulsifiers were found to be greater compared to IPA-SSOS made using isopropanol-dispersed OSA. FT-IR showed that 1.00% SP-SSOS and IPA-SSOS had two new characteristic peaks at 1572 cm–1 and 1726 cm–1, with 1.00% SP-SSOS having a stronger peak intensity. Confocal laser scanning microscopy confirmed that the fluorescence intensity of the fluorescence-labeled OS group was slightly stronger in 1.00% SP-SSOS, and a few starch particles contained OS groups inside. The results indicated that the use of high-pressure homogenization and emulsifiers to disperse OSA into micron-sized oily droplets for esterification could increase the contact area between OSA and starch, improving the efficiency of the esterification reaction. To summarize, it is possible to produce SSOS by utilizing the OSA emulsification technique as an alternative to organic reagents for dispersing OSA. This study would provide a reference for the application of an alcohol-free esterification reaction system in the large-scale industrial production of SSOS.

tapioca starch  /  non-alcohol esterification  /  starch sodium octenyl succinate  /  degree of substitution  /  confocal laser scanning microscopy
Yuanyuan GAO, Ruyi LI, Yingying LI, Wei ZHOU, Xiaobing HUANG, Shaodan PENG, Jihua LI. Preparation and Characterization of Tapioca Starch Sodium Octenyl Succinate with Non-alcohol Esterification[J]. Chinese Journal of Tropical Crops, 2024 , 45 (12) : 2719 -2727 . DOI: 10.3969/j.issn.1000-2561.2024.12.024
Year 2024 volume 45 Issue 12
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Article Info
doi: 10.3969/j.issn.1000-2561.2024.12.024
  • Receive Date:2024-07-29
  • Online Date:2026-06-23
  • Published:2024-12-25
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History
  • Received:2024-07-29
  • Revised:2024-08-13
Funding
Affiliations
    1.Agricultural Products Processing Research Institute / Key Laboratory of Tropical Crop Products Processing, Ministry of Agriculture and Rural Affairs, Zhanjiang, Guangdong 524001, China
    2.Chinese Academy of Tropical Agricultural Sciences, Haikou, Hainan 524091, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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