In order to optimize the cold start process of PEMFC,it is essential to provide sufficient feedback data. Common impedance spectroscopy and equivalent circuits cannot provide sufficient and real-time feedback due to long acquisition period. Therefore,the cold start impedance model is developed in COMSOL,and the change of impedance spectroscopy is analyzed in combination with experiments. The characteristic frequencies of 1kHz,50Hz and 1Hz are proposed in the high,medium and low frequency ranges respectively to characterize the cold start process of the fuel cell. The results show the above characteristic frequencies vary significantly in the pre-,mid- and post-cold start phases,with the change in impedance at characteristic frequencies of 1 kHz,50Hz and 1Hz of 0.38,0.31 and 1.47 respectively. It improves the real-time performance of data acquisition while retaining feature information compared to obtaining the full impedance spectroscopy and fitting the equivalent circuit. Therefore,the impedance at the characteristic frequency points can be used to characterize the cold start process,which provides real-time monitoring for the internal state of the cold start.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |