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Impedance Spectroscopy and Characteristic Frequency Analysis of the PEMFC Cold Start Process
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A’ bang Tao1, 2, Jianjian Tao1, 2, Xuezhe Wei1, 2
Automotive Engineering | 2024, 46(2) : 269 - 280
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Automotive Engineering | 2024, 46(2): 269-280
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Impedance Spectroscopy and Characteristic Frequency Analysis of the PEMFC Cold Start Process
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A’ bang Tao1, 2, Jianjian Tao1, 2, Xuezhe Wei1, 2
Affiliations
  • 1. School of Automotive Studies,Tongji University,Shanghai 201804
  • 2. Clean Energy Automotive Engineering Center,Tongji University,Shanghai 201804
Published: 2024-02-25 doi: 10.19562/j.chinasae.qcgc.2024.02.009
Outline
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In order to optimize the cold start process of PEMFC,it is essential to provide sufficient feedback data. Common impedance spectroscopy and equivalent circuits cannot provide sufficient and real-time feedback due to long acquisition period. Therefore,the cold start impedance model is developed in COMSOL,and the change of impedance spectroscopy is analyzed in combination with experiments. The characteristic frequencies of 1kHz,50Hz and 1Hz are proposed in the high,medium and low frequency ranges respectively to characterize the cold start process of the fuel cell. The results show the above characteristic frequencies vary significantly in the pre-,mid- and post-cold start phases,with the change in impedance at characteristic frequencies of 1 kHz,50Hz and 1Hz of 0.38,0.31 and 1.47 respectively. It improves the real-time performance of data acquisition while retaining feature information compared to obtaining the full impedance spectroscopy and fitting the equivalent circuit. Therefore,the impedance at the characteristic frequency points can be used to characterize the cold start process,which provides real-time monitoring for the internal state of the cold start.

PEMFC  /  impedance spectroscopy  /  cold start  /  analytical impedance model  /  equivalent circuit model
A’ bang Tao, Jianjian Tao, Xuezhe Wei. Impedance Spectroscopy and Characteristic Frequency Analysis of the PEMFC Cold Start Process[J]. Automotive Engineering, 2024 , 46 (2) : 269 -280 . DOI: 10.19562/j.chinasae.qcgc.2024.02.009
Year 2024 volume 46 Issue 2
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Article Info
doi: 10.19562/j.chinasae.qcgc.2024.02.009
  • Receive Date:2023-07-02
  • Online Date:2025-07-20
  • Published:2024-02-25
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  • Received:2023-07-02
  • Revised:2023-07-30
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Affiliations
    1. School of Automotive Studies,Tongji University,Shanghai 201804
    2. Clean Energy Automotive Engineering Center,Tongji University,Shanghai 201804
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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