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Determination of Impurity Elements in Primary Magnesium Ingots by ICP-AES and X-Ray Fluorescence Spectroscopy
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Fanjiao Meng, Hua Ma, Donghui Wang, Yang Cao, Dantong Zhou, Hongliang Li
Automobile Technology & Material | 2025, (8) : 51 - 55
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Automobile Technology & Material | 2025, (8): 51-55
Original article
Determination of Impurity Elements in Primary Magnesium Ingots by ICP-AES and X-Ray Fluorescence Spectroscopy
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Fanjiao Meng, Hua Ma, Donghui Wang, Yang Cao, Dantong Zhou, Hongliang Li
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  • Liaoyang Xiangyu Aluminum Industry Co., Ltd., Liaoyang 111003
Published: 2025-08-20 doi: 10.19710/J.cnki.1003-8817.20250031
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To ensure the purity during the aluminum alloy alloying process, it is necessary to control the impurity content in primary alloy ingots. The contents of silicon, iron, copper, aluminum, manganese, and nickel impurities in primary magnesium ingots are determined using Inductively Coupled Plasma Atomic Emission Spectrometry (ICP-AES) and X-Ray Fluorescence spectrometry (XRF). For ICP-AES, samples are dissolved with hydrogen peroxide-hydrochloric acid, and the spectral lines are optimized along with the matrix-matching method, achieving a detection limit of 0.000 01%~0.000 27%, a spike recovery rate of 92%~102%, and a repeatability RSD of <2.3%. For XRF, the optimal analysis conditions are determined, with a detection range of 0.000 1%~0.100 0% and a repeatability RSD of ≤3.1%. The results indicate that both methods exhibit good accuracy and repeatability, with ICP-AES offering higher sensitivity, while XRF is more suitable for rapid and non-destructive testing.

ICP-AES  /  Primary magnesium ingots  /  Fluorescence spectroscopy  /  Impurity elements
Fanjiao Meng, Hua Ma, Donghui Wang, Yang Cao, Dantong Zhou, Hongliang Li. Determination of Impurity Elements in Primary Magnesium Ingots by ICP-AES and X-Ray Fluorescence Spectroscopy[J]. Automobile Technology & Material, 2025 , (8) : 51 -55 . DOI: 10.19710/J.cnki.1003-8817.20250031
Year 2025 volume Issue 8
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doi: 10.19710/J.cnki.1003-8817.20250031
  • Online Date:2025-10-29
  • Published:2025-08-20
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    Liaoyang Xiangyu Aluminum Industry Co., Ltd., Liaoyang 111003
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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