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Experimental investigation of pressure, temperature, and salinity effects on the interfacial tension of H2/brine/cushion gases: Implications for H2 geo-storage
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Fatemeh Daraiia, Payam Moradia, *, Seyed Ali Bahreinia, Sina Anvarib
Petroleum Research | 2026, 11(2) : 545 - 555
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Petroleum Research | 2026, 11(2): 545-555
Full Length Article
Experimental investigation of pressure, temperature, and salinity effects on the interfacial tension of H2/brine/cushion gases: Implications for H2 geo-storage
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Fatemeh Daraiia, Payam Moradia, *, Seyed Ali Bahreinia, Sina Anvarib
Affiliations
  • aDepartment of Petroleum Engineering, Abadan Faculty of Petroleum Engineering, Petroleum University of Technology (PUT), Abadan, Iran
  • bSchool of Mining Engineering, College of Engineering, University of Tehran, Tehran, Iran
Published: 2026-06-10 doi: 10.1016/j.ptlrs.2025.11.004
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Underground hydrogen storage (UHS) in saline aquifers is a promising solution for large-scale, long-duration energy storage in a low-carbon energy system. Cushion gases, such as N2, CO2, and CH4, are commonly used to regulate reservoir pressure and enhance storage efficiency. However, despite recent advancements in understanding the interfacial tension (IFT) behavior of H2–gas mixtures in contact with brine under reservoir conditions, key gaps persist in systematic data for H2–cushion gas mixtures (e.g., with N2, CO2, and CH4) across specific thermophysical ranges, despite its influenceon capillary sealing, gas mobility, and recovery. This study presents systematic experimental measurements of IFT and density for H2–N2, H2–CO2, and H2–CH4 gas mixtures (70:30 mol%) with both distilled water and brine (30,000 ppm NaCl) at different temperatures (25, 50, and 70 °C) and pressures (1, 5, and 10 MPa). The IFT was measured using a high-pressure, high-temperature drop tensiometer, and density was obtained via an Anton Paar DMA 4500 densitometer. Results show a consistent decrease in IFT with rising temperature and pressure across all systems. Notably, the H2–CH4 mixture exhibited an IFT of 69.4 mN/m in distilled water at 25 °C and 1 MPa, decreasing to 57.3 mN/m at 70 °C; in contrast, the same mixture in 30,000 ppm brine showed a larger reduction from 61.3 mN/m to 47.8 mN/m under identical conditions, highlighting the amplifying effect of salinity on IFT decline. Among the gas mixtures, CH4 yielded the approximately lowest overall IFT values, favoring injectivity, whereas N2 maintained the highest IFT, supporting enhanced capillary retention. These findings address a critical data gap for realistic cushion gas performance and provide foundational insight for modeling UHS in saline aquifers.

Underground hydrogen storage  /  Cushion gas  /  Interfacial tension  /  High-pressure measurements
Fatemeh Daraii, Payam Moradi, Seyed Ali Bahreini, Sina Anvari. Experimental investigation of pressure, temperature, and salinity effects on the interfacial tension of H2/brine/cushion gases: Implications for H2 geo-storage[J]. Petroleum Research, 2026 , 11 (2) : 545 -555 . DOI: 10.1016/j.ptlrs.2025.11.004
Year 2026 volume 11 Issue 2
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Article Info
doi: 10.1016/j.ptlrs.2025.11.004
  • Receive Date:2025-05-14
  • Online Date:2026-07-29
  • Published:2026-06-10
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  • Received:2025-05-14
  • Revised:2025-11-19
  • Accepted:2025-11-21
Affiliations
    aDepartment of Petroleum Engineering, Abadan Faculty of Petroleum Engineering, Petroleum University of Technology (PUT), Abadan, Iran
    bSchool of Mining Engineering, College of Engineering, University of Tehran, Tehran, Iran

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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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