Underground hydrogen storage (UHS) in saline aquifers is a promising solution for large-scale, long-duration energy storage in a low-carbon energy system. Cushion gases, such as N2, CO2, and CH4, are commonly used to regulate reservoir pressure and enhance storage efficiency. However, despite recent advancements in understanding the interfacial tension (IFT) behavior of H2–gas mixtures in contact with brine under reservoir conditions, key gaps persist in systematic data for H2–cushion gas mixtures (e.g., with N2, CO2, and CH4) across specific thermophysical ranges, despite its influenceon capillary sealing, gas mobility, and recovery. This study presents systematic experimental measurements of IFT and density for H2–N2, H2–CO2, and H2–CH4 gas mixtures (70:30 mol%) with both distilled water and brine (30,000 ppm NaCl) at different temperatures (25, 50, and 70 °C) and pressures (1, 5, and 10 MPa). The IFT was measured using a high-pressure, high-temperature drop tensiometer, and density was obtained via an Anton Paar DMA 4500 densitometer. Results show a consistent decrease in IFT with rising temperature and pressure across all systems. Notably, the H2–CH4 mixture exhibited an IFT of 69.4 mN/m in distilled water at 25 °C and 1 MPa, decreasing to 57.3 mN/m at 70 °C; in contrast, the same mixture in 30,000 ppm brine showed a larger reduction from 61.3 mN/m to 47.8 mN/m under identical conditions, highlighting the amplifying effect of salinity on IFT decline. Among the gas mixtures, CH4 yielded the approximately lowest overall IFT values, favoring injectivity, whereas N2 maintained the highest IFT, supporting enhanced capillary retention. These findings address a critical data gap for realistic cushion gas performance and provide foundational insight for modeling UHS in saline aquifers.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |