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Preparation and mechanistic analysis of high-selectivity water control systems
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Zhizhen Lia, *, Weiyu Chena, b, c, Yanhui Sua, b, c, Xueli Genga, Bin Shia, Xiaobin Zhenga, Qian Zhoud, Gang Xied
Petroleum Research | 2026, 11(3) : 789 - 798
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Petroleum Research | 2026, 11(3): 789-798
• Full Length Article •
Preparation and mechanistic analysis of high-selectivity water control systems
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Zhizhen Lia, *, Weiyu Chena, b, c, Yanhui Sua, b, c, Xueli Genga, Bin Shia, Xiaobin Zhenga, Qian Zhoud, Gang Xied
Affiliations
  • aCNOOC EnerTech-Drilling & Production Co., Tanggu, Tianjin, 300452, China
  • bState Key Laboratory of Offshore Oil and Gas Exploition, Beijing, 100028, China
  • cCNOOC Energy Technology & Services Limited Key Laboratory of Enhanced Oil Recovery, Tanggu, Tianjin, 300452, China
  • dState Key Laboratory of Oil & Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan, 610500, China
Published: 2026-09-10 doi: 10.1016/j.ptlrs.2025.11.008
Outline
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This paper presents a highly selective water control system designed to address declining oil production in offshore wells caused by rising water cuts while overcoming the poor selectivity of current chemical water control materials. The system was developed by copolymerizing octadecyl methacrylate and butyl methacrylate, followed by emulsion polymerization to prepare oil-soluble polymers. This resulted in a water-dispersible, high-selectivity water control system in the form of an emulsion dispersion. The feasibility of its field application was assessed via median particle size and reservoir stability tests, and the system's water control performance, visual performance, and underlying mechanism were evaluated. The test results showed that the median droplet diameter of the emulsion in the system was 0.431 μm, and it remained stable for at least 8 h under reservoir conditions. The system demonstrated excellent selective water-control capabilities, with a water-phase permeability blocking rate of 82.42% and an oil-phase permeability blocking rate of 5.02%. The mechanism of action was further explored via visualized flat plate tests and low-field nuclear magnetic resonance scanning displacement experiments on rock cores. The findings suggest that oil-soluble particles exhibit effective selective water-control performance and can be applied in water control operations in offshore oil fields.

High-selectivity  /  Oil solubility  /  Water control  /  Oil-in-water emulsion
Zhizhen Li, Weiyu Chen, Yanhui Su, Xueli Geng, Bin Shi, Xiaobin Zheng, Qian Zhou, Gang Xie. Preparation and mechanistic analysis of high-selectivity water control systems[J]. Petroleum Research, 2026 , 11 (3) : 789 -798 . DOI: 10.1016/j.ptlrs.2025.11.008
  • Research Project of Engineering Technology Company, CNOOC Energy Technology & Services Limited(SSKJ-CG-GJ-2025-04)
  • Director's Fund of the National Key Laboratory of Efficient Development of Offshore Oil and Gas(KJQZ-2024-2101)
Year 2026 volume 11 Issue 3
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Article Info
doi: 10.1016/j.ptlrs.2025.11.008
  • Receive Date:2025-03-27
  • Online Date:2026-10-14
  • Published:2026-09-10
Article Data
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History
  • Received:2025-03-27
  • Revised:2025-11-22
  • Accepted:2025-11-23
Funding
Research Project of Engineering Technology Company, CNOOC Energy Technology & Services Limited(SSKJ-CG-GJ-2025-04)
Director's Fund of the National Key Laboratory of Efficient Development of Offshore Oil and Gas(KJQZ-2024-2101)
Affiliations
    aCNOOC EnerTech-Drilling & Production Co., Tanggu, Tianjin, 300452, China
    bState Key Laboratory of Offshore Oil and Gas Exploition, Beijing, 100028, China
    cCNOOC Energy Technology & Services Limited Key Laboratory of Enhanced Oil Recovery, Tanggu, Tianjin, 300452, China
    dState Key Laboratory of Oil & Gas Reservoir Geology and Exploitation, Southwest Petroleum University, Chengdu, Sichuan, 610500, China

Corresponding:

* E-mail address: (Z. Li).
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
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属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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