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A review on advancing clay-based geopolymers for high-temperature oil well cements: Mechanisms, durability, and applications
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Barima Moneya, Rayan Hassan Modathera, David Abutua, Norasyikin Ismaila, Augustine Agia, b, Francis Nyaha, Siti Qurratu' Aini Mahata, *
Petroleum Research | 2026, 11(1) : 274 - 296
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Petroleum Research | 2026, 11(1): 274-296
• Review Article •
A review on advancing clay-based geopolymers for high-temperature oil well cements: Mechanisms, durability, and applications
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Barima Moneya, Rayan Hassan Modathera, David Abutua, Norasyikin Ismaila, Augustine Agia, b, Francis Nyaha, Siti Qurratu' Aini Mahata, *
Affiliations
  • aFaculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuhraya Persiaran Tun Khalil Yaakob Kuantan, Pahang, 26300, Malaysia
  • bCentre for Research in Advanced Fluid and Processes (Fluid Centre), Universiti Malaysia Pahang Al-Sultan Abdullah, Gambang, Pahang, 26300, Malaysia
Published: 2026-03-10 doi: 10.1016/j.ptlrs.2025.08.005
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Geopolymers are promising alternatives to Portland cement due to their lower carbon footprint, superior mechanical strength, durability, and reduced shrinkage. However, inconsistent data and significant variations in experimental results highlight the uncertainty surrounding the reaction mechanisms of clay-based geopolymers (CBGs) in high-temperature oil wells. This review provides critical insights into these mechanisms and summarizes CBG synthesis methods. It explores the reaction processes of CBGs under high-temperature oil well conditions and analyzes the variables influencing these mechanisms. This review also examines the application of CBGs in oil wells, focusing on the challenges and potential solutions. Laboratory studies show that Portland cement degrades at temperatures above 300 ℉ (150 ℃), while CBGs maintain their integrity and strength at temperatures up to 1500 ℉ (815 ℃). This makes them particularly suitable for high-temperature geothermal wells and high-pressure, hightemperature oil well cementing. The dominant reaction mechanisms of CBGs include chemical reactivity, dissolution, gelation, polymerization, and growth. These findings highlight the potential of CBGs in addressing the challenges of high-temperature oil wells, thereby paving the way for further research in this area.

Clay geopolymers  /  Reaction mechanisms  /  Oil well cement  /  Low carbon footprint  /  Geopolymerization
Barima Money, Rayan Hassan Modather, David Abutu, Norasyikin Ismail, Augustine Agi, Francis Nyah, Siti Qurratu' Aini Mahat. A review on advancing clay-based geopolymers for high-temperature oil well cements: Mechanisms, durability, and applications[J]. Petroleum Research, 2026 , 11 (1) : 274 -296 . DOI: 10.1016/j.ptlrs.2025.08.005
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  • Ministry of Higher Education, Malaysia and Universiti Malaysia Pahang Al-Sultan Abdullah(RDU 220375; RDU 233305)
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Year 2026 volume 11 Issue 1
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Article Info
doi: 10.1016/j.ptlrs.2025.08.005
  • Receive Date：2025-02-10
  • Online Date：2026-10-14
  • Published：2026-03-10
Article Data
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History
  • Received：2025-02-10
  • Revised：2025-08-18
  • Accepted：2025-08-18
Funding
Ministry of Higher Education, Malaysia and Universiti Malaysia Pahang Al-Sultan Abdullah(RDU 220375; RDU 233305)
Affiliations
    aFaculty of Chemical and Process Engineering Technology, Universiti Malaysia Pahang Al-Sultan Abdullah, Lebuhraya Persiaran Tun Khalil Yaakob Kuantan, Pahang, 26300, Malaysia
    bCentre for Research in Advanced Fluid and Processes (Fluid Centre), Universiti Malaysia Pahang Al-Sultan Abdullah, Gambang, Pahang, 26300, Malaysia

Corresponding:

* E-mail address: (S.Q.A. Mahat).
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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