Enhancing photocatalytic nitrogen fixation through controlled acid corrosion of 1D TiO<sub>2</sub> nanobelts

Enhancing photocatalytic nitrogen fixation through controlled acid corrosion of 1D TiO₂ nanobelts

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Guanzheng Liu^a, Mengyu Wang^a, Jianing Huang^a, Chunyuan Li^a, Junkai Ren^b^,^*, Qi Wang^a, Haili Pang^a, Hui Zhang^a, Xiaoxia Bai^a^,^**

Progress in Natural Science: Materials International | 2026, 36(1) : 84 - 93

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Progress in Natural Science: Materials International | 2026, 36(1): 84-93

• Research Article •

Enhancing photocatalytic nitrogen fixation through controlled acid corrosion of 1D TiO₂ nanobelts

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Guanzheng Liu^a, Mengyu Wang^a, Jianing Huang^a, Chunyuan Li^a, Junkai Ren^b^,^*, Qi Wang^a, Haili Pang^a, Hui Zhang^a, Xiaoxia Bai^a^,^**

Affiliations

^aKey Laboratory of High-Orbits-Electron Materials and Protection Technology for Aerospaceare, School of Advanced Materials and Nanotechnology, Xidian University, Xi'an, 710126, China

^bSchool of Physics, Xidian University, Xi'an, 710126, China

Published: 2026-02-22 doi: 10.1016/j.pnsc.2025.11.004

Outline

Abstract

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Photocatalytic nitrogen reduction to produce ammonia under ambient conditions is a promising green route. In this study, we demonstrate that one-dimensional (1D) TiO₂ nanobelts, prepared via a facile hydrothermal method, can convert gaseous dinitrogen to ammonia in pure water under light irradiation. The photocatalytic ammonia production performance of TiO₂ nanobelts can be further enhanced through acid corrosion treatment, which generates secondary nanostructures. These surface nanostructures serve as potential catalytically active sites for nitrogen adsorption and reduction. Both photoelectrochemical measurements and photoluminescence spectra confirm that the optimized TiO₂ nanobelts exhibit improved charge separation. Given their excellent stability and unique 1D nanostructure, acid-corroded TiO₂ nanobelts are a promising support material for constructing high-performance composite photocatalysts for nitrogen fixation.

Key words

TiO₂ nanobelt / Hydrothermal synthesis / Acid corrosion / Photocatalytic nitrogen reduction / Ammonia

Cite this Article

. Enhancing photocatalytic nitrogen fixation through controlled acid corrosion of 1D₂TiO nanobelts. 自然科学进展：国际材料（英文）, 2026 , 36 (1) : 84 -93 . DOI: 10.1016/j.pnsc.2025.11.004

Guanzheng Liu, Mengyu Wang, Jianing Huang, Chunyuan Li, Junkai Ren, Qi Wang, Haili Pang, Hui Zhang, Xiaoxia Bai. Enhancing photocatalytic nitrogen fixation through controlled acid corrosion of 1D TiO₂ nanobelts[J]. Progress in Natural Science: Materials International, 2026 , 36 (1) : 84 -93 . DOI: 10.1016/j.pnsc.2025.11.004

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Funding

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National Natural Science Foundation of China(6217032156; 52202294)
National Key Research and Development Program of China(2019YFE0121600)
Xidian University Specially Funded Project for Interdisciplinary Exploration(TZJH2024046)
Shaanxi Province high foreign expertise project(90728220020)
Research start-up funds(10251220007)
Fundamental Research Funds for the Central Universities(JB211412)

Appendix

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Year 2026 volume 36 Issue 1

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133

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Article Info

doi: 10.1016/j.pnsc.2025.11.004

Receive Date：2025-08-05
Online Date：2026-06-03
Published：2026-02-22

Article Data

Affiliations

History

Received：2025-08-05
Revised：2025-10-30
Accepted：2025-11-04

Funding

National Natural Science Foundation of China(6217032156; 52202294)

National Key Research and Development Program of China(2019YFE0121600)

Xidian University Specially Funded Project for Interdisciplinary Exploration(TZJH2024046)

Shaanxi Province high foreign expertise project(90728220020)

Research start-up funds(10251220007)

Fundamental Research Funds for the Central Universities(JB211412)

Affiliations

^aKey Laboratory of High-Orbits-Electron Materials and Protection Technology for Aerospaceare, School of Advanced Materials and Nanotechnology, Xidian University, Xi'an, 710126, China

^bSchool of Physics, Xidian University, Xi'an, 710126, China

Corresponding:

^* E-mail addresses: renjunkai@xidian.edu.cn (J. Ren)

^** E-mail addresses: xxbai@xidian.edu.cn (X. Bai).

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表12种不同金属材料的力学参数

科 Family	属数 Number of genus	种数 Number of species	占总种数比例 Percentage of total species (%)	属 Genus	种数 Number of species	占总种数比例 Percentage of total species (%)
鹅膏菌科Amanitaceae	2	11	5.26	鹅膏菌属 Amanita	10	4.78
小菇科 Mycenaceae	2	12	5.74	丝盖伞属 Inocybe	5	2.39
多孔菌科 Polyporaceae	8	14	6.70	蜡蘑属 Laccaria	5	2.39
红菇科 Russulaceae	3	23	11.00	小皮伞属 Marasmius	6	2.87
				小菇属 Mycena	11	5.26
				光柄菇属 Pluteus	5	2.39
				红菇属 Russula	17	8.13
				栓菌属 Trametes	5	2.39

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