CdS thin films were fabricated by annealing precursors which were deposited using the method of Sputtering, Evaporation and Sputtering (SES). Effect of sputtering time and RF power on the structural, compositional, surface morphology and optical properties of CdS thin films was investigated by X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersion spectrometer (EDS), UV-Vis spectrophotometer and photoluminescence (PL). The results reveal that the properties and growth of the obtained CdS films are greatly influenced by the second sputtering time rather than the first sputtering time. The deposited precursors are substrate/Cd/CdS, and transformed to CdS after annealing. The CdS films are hexagonal structure with a preferred orientation along (002) plane. Besides, the dense CdS films without cracks or pinholes have S/Cd atomic ratios of 0.87-0.99. Additionally, the grain size, morphology and composition of CdS films change with increasing RF power from 80 W to 150 W. All CdS films have a high average transmittance and band gaps of 2.25-2.43 eV. The PL emission peaks at 530 nm for CdS thin films are possibly caused by the band edge emission while the PL emission peaks at 680 nm arise from sulfur vacancies.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |