Safety and stability is the premise of intelligent mine reform. In order to improve the scientific management level of mine enterprises and reduce the accident rate, based on social information processing theory, self-determination theory and affective event theory, a moderated chain mediation model was constructed with taking charge behavior and harmonious safety passion as mediating variables and organizational resilience as moderating variables. A questionnaire survey was conducted to collect data from 400 miners in a coal mine in Shanxi Province in two stages, with a total of 364 valid questionnaires collected. And the hypothesis model was verified by empirical research method. The results are concluded as follows. Firstly, resonant leadership has a positive effect on miners' proactive accountability behavior. Secondly, resonant leadership positively affected miners' proactive accountability behavior through the independent mediating effect of perceived insider status and harmonious safety passion, as well as the chain mediating effect of perceived insider status and harmonious safety passion. Thirdly, organizational resilience can positively regulate the relationship between harmonious safety passion and proactive accountability behavior, and positively regulate the chain mediation relationship between perceived insider status and harmonious safety passion.