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Research on the Beneficiation Process of a Fluorite-Rare Earth Polymetallic Ore in Henan Province
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Jie LI1, 2, Zhongxu QI1, 2, 3, Shihong XU3, 4, Xu JIANG1, 2, Zhiwei ZHU1, 2
Mining Research and Development | 2026, 46(4) : 240 - 248
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Mining Research and Development | 2026, 46(4): 240-248
Research on the Beneficiation Process of a Fluorite-Rare Earth Polymetallic Ore in Henan Province
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Jie LI1, 2, Zhongxu QI1, 2, 3, Shihong XU3, 4, Xu JIANG1, 2, Zhiwei ZHU1, 2
Affiliations
  • 1.Changsha Institute of Mining Research Co., Ltd., Changsha, Hunan 410012, China
  • 2.Hunan Engineering and Technology Research Center for Comprehensive Utilization of Mine Solid Waste, Changsha, Hunan 410012, China
  • 3.School of Minerals Processing and Bioengineering, Central South University, Changsha, Hunan 410083, China
  • 4.Key Laboratory of Clean and Efficient Utilization of Strategic Calcium-Containing Mineral Resources of Hunan Province, Central South University, Changsha, Hunan 410083, China
Published: 2026-04-25
Outline
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To effectively solve the dual technical problems of separation of fluorite, rare earth and minerals containing calcium, barium/strontium separation and separation of fluorite and rare earth in a fluorite-rare earth polymetallic ore in Henan Province, as well as the comprehensive utilization of low-grade molybdenum and lead, the beneficiation process was studied. The grade of CaF2 and REO in the fluorite-rare earth polymetallic ore are 21.73% and 1.56%, respectively, accompanied by molybdenum and lead, and their grades are 0.055% and 0.54%, respectively. The content of calcite and barite in the gangue component is high, and it is closely related to fluorite and rare earth. The principle process of "first flotation enrichment of molybdenum and lead, then recovery of fluorite and rare earth" and the mineral processing scheme of "fluorite and rare earth mixed flotation" + "magnetic-gravity combined separation" were adopted. Modified fatty acid collectors CK-1 and CK-2 were used in combination, and calcium, barium/strontium gangue was strengthened and inhibited by acidified water glass. The whole process closed circuit test obtained lead concentrate with a Pb grade of 55.12% and a Pb recovery rate of 33.63%; molybdenum lead intermediate ore with a Mo grade of 3.28%, a Pb grade of 7.95%, a Mo recovery rate of 56.86%, and a Pb recovery rate of 13.03%; fluorite concentrate with a CaF2 grade of 95.41% and a CaF2 recovery rate of 79.32%; rare earth concentrate with a REO grade of 56.83% and a REO recovery rate of 45.10%. The process realizes the efficient recovery of fluorite and rare earth and the comprehensive utilization of molybdenum and lead, which provides technical support for the development and utilization of the complex polymetallic ore.

Fluorite-rare earth polymetallic ore  /  Beneficiation process  /  Separation of fluorite and rare earth  /  Comprehensive recovery
李杰, 祁忠旭, 徐世红, 江旭, 朱志伟. 河南某萤石-稀土多金属矿选矿工艺研究. 矿业研究与开发, 2026 , 46 (4) : 240 -248 .
Jie LI, Zhongxu QI, Shihong XU, Xu JIANG, Zhiwei ZHU. Research on the Beneficiation Process of a Fluorite-Rare Earth Polymetallic Ore in Henan Province[J]. Mining Research and Development, 2026 , 46 (4) : 240 -248 .
Year 2026 volume 46 Issue 4
40
13
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  • Receive Date:2025-07-11
  • Online Date:2026-10-29
  • Published:2026-04-25
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  • Received:2025-07-11
Funding
Affiliations
    1.Changsha Institute of Mining Research Co., Ltd., Changsha, Hunan 410012, China
    2.Hunan Engineering and Technology Research Center for Comprehensive Utilization of Mine Solid Waste, Changsha, Hunan 410012, China
    3.School of Minerals Processing and Bioengineering, Central South University, Changsha, Hunan 410083, China
    4.Key Laboratory of Clean and Efficient Utilization of Strategic Calcium-Containing Mineral Resources of Hunan Province, Central South University, Changsha, Hunan 410083, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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