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Action Mechanism of Thiol Collectors in the Flotation Separation of Chalcopyrite and Pyrite
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Yujiao HUANG1, 2, Hengguang GU1, 2, Hanquan ZHANG1, 2
Mining Research and Development | 2026, 46(3) : 273 - 280
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Mining Research and Development | 2026, 46(3): 273-280
Action Mechanism of Thiol Collectors in the Flotation Separation of Chalcopyrite and Pyrite
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Yujiao HUANG1, 2, Hengguang GU1, 2, Hanquan ZHANG1, 2
Affiliations
  • 1.School of Resources & Safety Engineering, Wuhan Institute of Technology, Wuhan, Hubei 430074, China
  • 2.State Key Laboratory of Green and Efficient Development of Phosphorus Rock and Its Associated Resources, Wuhan, Hubei 430073, China
Published: 2026-03-25
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To address the low flotation separation efficiency of chalcopyrite and pyrite, a novel thiol collector (930 agent) was adopted in flotation tests. Its selective adsorption mechanism was revealed by Fourier transform infrared spectroscopy analysis, and its effectiveness was verified through mineral flotation tests. The test results show that the novel environment-friendly and high-efficiency collector 930 agent, obtained by functional group structure reconstruction based on thiol collectors, increases the copper recovery of concentrate by 12.27% and 4.77%, the sulfur recovery of concentrate by 13.84% and 1.99%, and raises the sulfur grade of sulfur concentrate by 3.37% and 3.00% respectively, compared with the traditional collectors ethyl xanthate and butyl xanthate. The use of the new 930 collector optimizes the selectivity of copper-sulfur separation, provides a novel agent scheme with high selectivity and environmental friendliness for sulfide ore flotation separation, and is of great significance for reducing smelting costs and alkaline wastewater discharge.

Chalcopyrite  /  Pyrite  /  Flotation  /  Thiol collector
黄玉娇, 顾恒光, 张汉泉. 巯基类捕收剂在黄铜矿与黄铁矿浮选分离中的作用机理. 矿业研究与开发, 2026 , 46 (3) : 273 -280 .
Yujiao HUANG, Hengguang GU, Hanquan ZHANG. Action Mechanism of Thiol Collectors in the Flotation Separation of Chalcopyrite and Pyrite[J]. Mining Research and Development, 2026 , 46 (3) : 273 -280 .
Year 2026 volume 46 Issue 3
42
13
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  • Receive Date:2025-03-19
  • Online Date:2026-10-29
  • Published:2026-03-25
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  • Received:2025-03-19
Affiliations
    1.School of Resources & Safety Engineering, Wuhan Institute of Technology, Wuhan, Hubei 430074, China
    2.State Key Laboratory of Green and Efficient Development of Phosphorus Rock and Its Associated Resources, Wuhan, Hubei 430073, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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