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Research on the Application of Compound Doped APAM in the Treatment of Limestone Sand-Making Wastewater
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Yi Luo1, Jiacheng Zhu1, 2, Yubin Qian3, Wenxu Zhang4, Tao Yan2
Mining Research and Development | 2026, 46(7) : 301 - 309
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Mining Research and Development | 2026, 46(7): 301-309
Research on the Application of Compound Doped APAM in the Treatment of Limestone Sand-Making Wastewater
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Yi Luo1, Jiacheng Zhu1, 2, Yubin Qian3, Wenxu Zhang4, Tao Yan2
Affiliations
  • 1.Department of Municipal and Environmental Engineering, Hebei University of Architecture Civil Engineering, Zhangjiakou, Hebei 075000, China
  • 2.Sinohydro Bureau 7 Co., Ltd., Chengdu, Sichuan 611730, China
  • 3.China National Building Material New Materials Co., Ltd., Jiujiang, Jiangxi 332200, China
  • 4.College of Water Resources and Civil Engineering, China Agricultural University, Beijing 100083, China
Published: 2026-07-25
Outline
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Anionic polyacrylamide (APAM) is the most widely used flocculant in the mining sand-making industry. The phenomenon of compound doping during its production is relatively common, which leads to the degradation of APAM flocculation performance. Flocculation sedimentation tests were conducted to systematically evaluate the effects of five compounds, including sodium chloride (NaCl), on the flocculation performance of APAM. The characteristics of doped APAM were characterized by using techniques such as X-ray diffraction (XRD), Fourier transform infrared spectroscopy (FTIR), and chemical titration. Cost-benefit analysis was employed to quantify the economic impact of the doping behavior. The results show that APAM achieves the optimal flocculation effect at a mass concentration of 0.1% and a dosage of 24 g/t. High compound dosages (≥30%) severely degrade the flocculation performance of APAM. Specifically, when the NaCl dosage is 50%, the median particle size of sludge flocs decreases from 95.3 μm to 41.3 μm, a reduction of 56.7%, and the settling time is extended to more than double, resulting in a significant decline in wastewater treatment efficiency. The established combined detection system integrating solid content measurement, FTIR, XRD, and chemical titration can specifically identify the doping components. The economic analysis indicates that 50% NaCl doping can reduce the production cost of APAM to 6 150 yuan/t, with a profit margin of 48.75%. The research results can provide a technical basis for the quality control of flocculants and the optimization of water treatment systems in sand-making plant.

Compound doping  /  APAM  /  Flocculation sedimentation  /  Economic analysis
罗义, 朱嘉成, 钱余斌, 张文旭, 闫涛. 化合物掺杂APAM在石灰岩制砂废水处理中的应用研究. 矿业研究与开发, 2026 , 46 (7) : 301 -309 .
Yi Luo, Jiacheng Zhu, Yubin Qian, Wenxu Zhang, Tao Yan. Research on the Application of Compound Doped APAM in the Treatment of Limestone Sand-Making Wastewater[J]. Mining Research and Development, 2026 , 46 (7) : 301 -309 .
Year 2026 volume 46 Issue 7
65
7
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Article Info
  • Receive Date:2025-07-01
  • Online Date:2026-10-27
  • Published:2026-07-25
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  • Received:2025-07-01
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Affiliations
    1.Department of Municipal and Environmental Engineering, Hebei University of Architecture Civil Engineering, Zhangjiakou, Hebei 075000, China
    2.Sinohydro Bureau 7 Co., Ltd., Chengdu, Sichuan 611730, China
    3.China National Building Material New Materials Co., Ltd., Jiujiang, Jiangxi 332200, China
    4.College of Water Resources and Civil Engineering, China Agricultural University, Beijing 100083, China
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表12种不同金属材料的力学参数
科
Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)
属
Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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