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Progress in Research of Preparation and Modification of Lithium Manganese Iron Phosphate and Challenges in Industrialization
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Sha LI1, 2, Wenbin LI1, 2, Hongxu LI1, 2, Youyuan ZHOU3, Keyuan FENG1, 2, Yizhou CAO1, 2, Lingwen ZHANG4
Mining and Metallurgical Engineering | 2025, 45(6) : 208 - 215
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Mining and Metallurgical Engineering | 2025, 45(6): 208-215
• MATERIALS •
Progress in Research of Preparation and Modification of Lithium Manganese Iron Phosphate and Challenges in Industrialization
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Sha LI1, 2, Wenbin LI1, 2, Hongxu LI1, 2, Youyuan ZHOU3, Keyuan FENG1, 2, Yizhou CAO1, 2, Lingwen ZHANG4
Affiliations
  • 1.Zijin Mining New Energy and New Material Technology (Changsha) Co., Ltd., Changsha 410000, Hunan, China
  • 2.Zijin Mining Group Co., Ltd., Shanghang 364200, Fujian, China
  • 3.Changsha Research Institute of Mining and Metallurgy Co., Ltd., Changsha 410012, Hunan, China
  • 4.Fujian Zijin Lithium Energy Material Technology Co., Ltd., Shanghang 364200, Fujian, China
doi: 10.3969/j.issn.0253-6099.2025.06.036
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After systematical analysis of the material characteristics of lithium manganese iron phosphate (LMFP) and comprehensive summarization of all preparation technologies based on the current research status of enterprises, the mechanisms of modification strategies, including optimization of manganese-iron ratio, nano-crystallization, morphology and structure regulation, surface coating and ion doping, for enhancing electrochemical performance of LMFP are reviewed. Besides, aiming at the pain points in industrialization, a feasible development path is proposed, which can provide theoretical support and guidance in engineering projects of transition of LMFP from laboratory innovation research to large-scale production, and also facilitate the breakthrough in its commercialization in the fields of energy storage and power batteries.

lithium-ion battery  /  cathode material  /  lithium manganese iron phosphate  /  industrialization  /  lithium iron phosphate  /  lithium manganese phosphate  /  modification strategy  /  preparation method
李厦, 李文彬, 李宏煦, 周友元, 冯克源, 曹一洲, 张玲文. 磷酸锰铁锂制备和改性研究进展及产业化应用挑战. 矿冶工程杂志, 2025 , 45 (6) : 208 -215 . DOI: 10.3969/j.issn.0253-6099.2025.06.036
Sha LI, Wenbin LI, Hongxu LI, Youyuan ZHOU, Keyuan FENG, Yizhou CAO, Lingwen ZHANG. Progress in Research of Preparation and Modification of Lithium Manganese Iron Phosphate and Challenges in Industrialization[J]. Mining and Metallurgical Engineering, 2025 , 45 (6) : 208 -215 . DOI: 10.3969/j.issn.0253-6099.2025.06.036
Appendix
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Year 2025 volume 45 Issue 6
118
26
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Article Info
doi: 10.3969/j.issn.0253-6099.2025.06.036
  • Receive Date：2025-05-20
  • Online Date：2026-10-08
Article Data
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  • Received：2025-05-20
Affiliations
    1.Zijin Mining New Energy and New Material Technology (Changsha) Co., Ltd., Changsha 410000, Hunan, China
    2.Zijin Mining Group Co., Ltd., Shanghang 364200, Fujian, China
    3.Changsha Research Institute of Mining and Metallurgy Co., Ltd., Changsha 410012, Hunan, China
    4.Fujian Zijin Lithium Energy Material Technology Co., Ltd., Shanghang 364200, Fujian, China
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表12种不同金属材料的力学参数
科
Family		 属数
Number of
genus		 种数
Number of
species		 占总种数比例
Percentage of
total species (%)		 属
Genus		 种数
Number of
species		 占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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