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Experimental Study on Recovering Copper from Acid Leachate of Waste Circuit Boards by Solvent Extraction
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Lin LIU1, 2, 3, Wei WANG1, 2, 3, Hongzhao LIU1, 2, 3, Yaohua CAO1, 2, 3, Ke WANG1, 2, 3, Junli ZHAO4
Mining and Metallurgical Engineering | 2025, 45(3) : 158 - 162
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Mining and Metallurgical Engineering | 2025, 45(3): 158-162
METALLURGY
Experimental Study on Recovering Copper from Acid Leachate of Waste Circuit Boards by Solvent Extraction
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Lin LIU1, 2, 3, Wei WANG1, 2, 3, Hongzhao LIU1, 2, 3, Yaohua CAO1, 2, 3, Ke WANG1, 2, 3, Junli ZHAO4
Affiliations
  • 1.Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, CAGS, Zhengzhou 450006, Henan, China
  • 2.Key Laboratory of Evaluation and Utilization for Polymetallic Ores, MNR, Zhengzhou 450006, Henan, China
  • 3.Key Laboratory of Comprehensive Utilization of Gold Resource in Henan Province, Zhengzhou 450006, Henan, China
  • 4.Zhengzhou Institute of Emerging Industrial Technology, Zhengzhou 450003, Henan, China
Published: 2025-06-01 doi: 10.3969/j.issn.0253-6099.2025.03.026
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In order to recycle the waste circuit boards, the acid leachate with a copper content of 34.33 g/L was treated by adopting solvent extraction to recover the copper therein. The effects of extractant type, extraction time, phase ratio, extractant concentration, and extraction temperature on copper extraction efficiency were all investigated. The results show that with AD100 as the copper extractant, phase ratio (VO/VA) at 1∶3, and extractant concentration of 60%, an oscillating extraction at room temperature of 25 ℃ for 10 min can result in the copper extraction rate of 96.62%. Then, a back-extraction process is adopted to treat the organic phase with oxalic acid, producing copper oxalate, which can be calcined to obtained copper oxide products.

electronic solid waste  /  waste circuit board  /  copper recovery  /  AD100  /  solvent extraction
Lin LIU, Wei WANG, Hongzhao LIU, Yaohua CAO, Ke WANG, Junli ZHAO. Experimental Study on Recovering Copper from Acid Leachate of Waste Circuit Boards by Solvent Extraction[J]. Mining and Metallurgical Engineering, 2025 , 45 (3) : 158 -162 . DOI: 10.3969/j.issn.0253-6099.2025.03.026
Year 2025 volume 45 Issue 3
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doi: 10.3969/j.issn.0253-6099.2025.03.026
  • Receive Date:2024-12-26
  • Online Date:2026-03-19
  • Published:2025-06-01
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  • Received:2024-12-26
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Affiliations
    1.Zhengzhou Institute of Multipurpose Utilization of Mineral Resources, CAGS, Zhengzhou 450006, Henan, China
    2.Key Laboratory of Evaluation and Utilization for Polymetallic Ores, MNR, Zhengzhou 450006, Henan, China
    3.Key Laboratory of Comprehensive Utilization of Gold Resource in Henan Province, Zhengzhou 450006, Henan, China
    4.Zhengzhou Institute of Emerging Industrial Technology, Zhengzhou 450003, Henan, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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