Based on the investigation of occurrence state, fluoride associated with barite was leached with HCl-AlCl3 by using Plackett-Burman design, and influences of HCl concentration, AlCl3 concentration, reaction temperature, reaction time, and liquid-to-solid ratio on fluorine leaching rate were investigated. It is found that the fluorine in barite mainly exists in the form of disseminated and banded fluorite. By using HCl at a concentration of 3 mol/L and AlCl3 at a concentration of 0.4 mol/L, after 30 min leaching reaction of ore sample with grain size of 48-75 μm, liquid-to-solid ratio of 10 mL/g, and stirring speed at 300 r/min, the leaching rate of fluorine can reach 93.20%, and the mass fraction of barite is 95.91%. Results show that all factors that influence fluorine leaching rate are arranged in descending order of importance as follows: reaction temperature > HCl concentration > reaction time > AlCl3 concentration > liquidto-solid ratio.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |