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Effect of Oxidative Roasting Pretreatment on Recycling of Anode Materials from Spent Lithium Iron Phosphate Batteries
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Haisen LI, Dingshan RUAN, Peng ZHANG, Zhiyuan MENG, You ZHOU, Qiang LI
Mining and Metallurgical Engineering | 2024, 44(4) : 105 - 108
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Mining and Metallurgical Engineering | 2024, 44(4): 105-108
SPECIAL ISSUE: BATTERY MATERIALS
Effect of Oxidative Roasting Pretreatment on Recycling of Anode Materials from Spent Lithium Iron Phosphate Batteries
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Haisen LI, Dingshan RUAN, Peng ZHANG, Zhiyuan MENG, You ZHOU, Qiang LI
Affiliations
  • Guangdong Brunp Recycling Technology Co, Ltd, Foshan 528137, Guangdong, China
Published: 2024-08-01 doi: 10.3969/j.issn.0253-6099.2024.04.020
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Cathode and anode materials in spent lithium iron phosphate battery powder are difficult to be separated by flotation. In order to solve this problem, it was proposed that lithium iron phosphate battery powder was pretreated by oxidative roasting, and then subjected to a flotation process for seperation between the cathode and anode materials of lithium iron phosphate. The results show that after lithium iron phosphate battery powder is pretreated by oxidative roasting at 500 ℃ for 30 minutes, the subsequent flotation process can lead to the graphite-based anode material with carbon grade up from 47.63% to 97.70%, and the cathode material with carbon grade down from 24.00% to 1.01%, presenting a significant separation effect. In comparison, the battery powder without pretreatment has cobweb-like long carbon-chain organic matter on its surface, which causes adhesion between cathode and anode materials of batteries, resulting in poor separation effect by flotation. The pretreatment of oxidative roasting can effectively eliminate the long carbon-chain organic matter on those cathode and anode materials, thus enhancing the difference in surface properties between cathode and anode materials. As a result, the enhanced flotation separation effect makes graphite-based anode material recycled from spent lithium iron phosphate batteries.

recycling of spent battery  /  lithium iron phosphate  /  recycling of anode material  /  oxidative roasting  /  surface modification  /  flotation  /  graphite-based anode material
Haisen LI, Dingshan RUAN, Peng ZHANG, Zhiyuan MENG, You ZHOU, Qiang LI. Effect of Oxidative Roasting Pretreatment on Recycling of Anode Materials from Spent Lithium Iron Phosphate Batteries[J]. Mining and Metallurgical Engineering, 2024 , 44 (4) : 105 -108 . DOI: 10.3969/j.issn.0253-6099.2024.04.020
Year 2024 volume 44 Issue 4
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doi: 10.3969/j.issn.0253-6099.2024.04.020
  • Receive Date:2024-02-19
  • Online Date:2026-03-18
  • Published:2024-08-01
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  • Received:2024-02-19
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    Guangdong Brunp Recycling Technology Co, Ltd, Foshan 528137, Guangdong, China
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https://castjournals.cast.org.cn/joweb/kygczz/EN/10.3969/j.issn.0253-6099.2024.04.020
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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