With an increase in Ni content, the capacity of high-nickel layered metal oxides (LiNixMnyCo1-x-yO2 (0.8≤x<1, NCM) greatly decreases. In view of such problem, it is proposed that singly-crystal NCM cathode material be modified by dual SiO2@Li2SiO3 coating to improve its electrochemical performance. During the synthesis process, the reaction of can consume the residue lithium on the material surface, thus improving diffusion kinetics of interface lithium ions and inhibiting side reaction at the interface. It is shown that the modified cathode material delivers a specific discharge capacity of 156.88 mAh/g after 120 cycles, with capacity retention rate of 70.52%.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |