Extraction of rhenium from low-grade molybdenum concentrate by adopting a process of oxidative volatilization followed by ion exchange was explored in experiments. Firstly, a two-stage high-temperature oxidative roasting was adopted to oxidize rhenium into Re2O7. Rhenium and molybdenum were effectively separated due to rhenium volatilizing into the flue gas. The volatilization rate of rhenium reached 85.42% after roasting process at 675 ℃. Then, the rhenium-containing flue gas was eluted to get rhenium-containing solution, in which rhenium was selectively extracted with D201×7 ion exchange resin. With the solution pH of 9, liquid/solid ratio of 50 mL/g, a 20 min adsorption at temperature of 35 ℃ brought the adsorption rate of Re up to 97.52% and the adsorption rate of Mo less than 20%. Finally, a product of ammonium rhenate was prepared by stepwise desorption followed by concentration and crystallization. By this process, the total recovery of Re can reach 70.68%.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |