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Preparation of Manganese-Containing Master Alloy and Its Application in Rare-Earth-Based Hydrogen Storage Alloys
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Bo ZHENG1, Maoliang XIE2, Quanbing REN1, Huasheng LAI2, Lan FENG1, Wenwen LIU2, Xiong PI1, Ronghua LI1, Hao LIN1
Mining and Metallurgical Engineering | 2025, 45(5) : 170 - 175
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Mining and Metallurgical Engineering | 2025, 45(5): 170-175
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Preparation of Manganese-Containing Master Alloy and Its Application in Rare-Earth-Based Hydrogen Storage Alloys
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Bo ZHENG1, Maoliang XIE2, Quanbing REN1, Huasheng LAI2, Lan FENG1, Wenwen LIU2, Xiong PI1, Ronghua LI1, Hao LIN1
Affiliations
  • 1.Jiangxi Jiangwu Haoyun Technology Co., Ltd., Nanchang 330096, Jiangxi, China
  • 2.Ganzhou Nonferrous Metallurgy Research Institute Co., Ltd., Ganzhou 341000, Jiangxi, China
Published: 2025-10-01 doi: 10.3969/j.issn.0253-6099.2025.05.030
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Manganese-containing master alloy was prepared by vacuum induction melting. Effects of factors, such as manganese source, Mn/Al mass ratio, preheating time, and refining time on the composition of the manganese-containing master alloy were studied, and the influence of manganese-containing master alloys replacing the traditional “Mn + Al” feed on the prepared manganese-containing AB5-type rare-earth-based hydrogen storage alloy was also discussed. The experimental results show that compared to manganese powder, manganese flakes as manganese source can bring higher melting yield. Manganese-containing master alloys can be formed with different Mn/Al mass ratios. As the preheating time is prolonged, the melting yield firstly increases and then decreases, and the optimal condition for preheating is 10 minutes at a power of 4 kW. As the refining time increases, the melting yield decreases slightly, and the optimal condition for refining is 1 minute at a power of 15 kW. The average melting yields of rare-earth-based hydrogen storage alloy prepared with MnAlNi alloy and MnAl alloy are increased by 0.37% and 0.78% respectively than that with “Mn + Al” as raw material. The preparation of AB5-type rare-earth-based hydrogen storage alloy with manganese-containing master alloy can optimize the yield, with the hydrogen storage performance not influenced. The application of this method in practical industrial production brings good effect.

vacuum induction melting  /  rare-earth-based hydrogen storage alloy  /  master alloy  /  manganese  /  AB5-type hydrogen storage alloy
Bo ZHENG, Maoliang XIE, Quanbing REN, Huasheng LAI, Lan FENG, Wenwen LIU, Xiong PI, Ronghua LI, Hao LIN. Preparation of Manganese-Containing Master Alloy and Its Application in Rare-Earth-Based Hydrogen Storage Alloys[J]. Mining and Metallurgical Engineering, 2025 , 45 (5) : 170 -175 . DOI: 10.3969/j.issn.0253-6099.2025.05.030
Year 2025 volume 45 Issue 5
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Article Info
doi: 10.3969/j.issn.0253-6099.2025.05.030
  • Receive Date:2025-04-20
  • Online Date:2026-03-18
  • Published:2025-10-01
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  • Received:2025-04-20
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    1.Jiangxi Jiangwu Haoyun Technology Co., Ltd., Nanchang 330096, Jiangxi, China
    2.Ganzhou Nonferrous Metallurgy Research Institute Co., Ltd., Ganzhou 341000, Jiangxi, China
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https://castjournals.cast.org.cn/joweb/kygczz/EN/10.3969/j.issn.0253-6099.2025.05.030
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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