The acid leaching solution of electrostatic precipitator dust from copper smelting has a high concentration of sulfuric acid, in which the iron and arsenic exist in the form of Fe3+and As5+, thus it is decided to adopt arsenic sulfide residue as the precipitant for copper precipitation. Firstly, an experiment was performed on the addition of arsenic sulfide residue in single Cu2+ and Fe3+ solution with different acid concentrations. Based on that, an experiment was performed for copper precipitation and arsenic leaching in the actual acid leaching solution. The results show that in the process of copper precipitation with arsenic sulfide residue, oxidation and reduction reactions between Fe3+ and S2- occur firstly, which is followed by oxidation and reduction reactions of As5+ and S2-, and finally a sulfurization reaction for precipitation of Cu2+. When the addition of arsenic sulfide residue is at an amount of 1.4 times the theoretical amount, it is shown that the copper precipitation rate is relatively higher, but the rate of arsenic dissolution is lower.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |