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Recovery of Antimony and Alkali from Arsenic-Alkali Slag and Solidification of Arsenic
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Dongsheng KANG1, Guizhong JIN1, Zhifeng XU2, Yudong YANG2, Yuhu LI2, Chengyong JIN1, Shen LUO1
Mining and Metallurgical Engineering | 2023, 43(4) : 125 - 130
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Mining and Metallurgical Engineering | 2023, 43(4): 125-130
METALLURGY
Recovery of Antimony and Alkali from Arsenic-Alkali Slag and Solidification of Arsenic
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Dongsheng KANG1, Guizhong JIN1, Zhifeng XU2, Yudong YANG2, Yuhu LI2, Chengyong JIN1, Shen LUO1
Affiliations
  • 1.Hsikwang Shan Twinkling Star Co Ltd, Lengshuijiang 417502, Hunan, China
  • 2.School of Metallurgical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China
Published: 2023-08-01 doi: 10.3969/j.issn.0253-6099.2023.04.027
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In order to achieve utilization of antimony and alkali in arsenic-alkali slag and solidification of arsenic, a new processing technique, consisting of separation antimony by water leaching, arsenic precipitation by hydrothermal reaction with lime, and alkali extraction by evaporation, was proposed to treat arsenic-alkali slag. Results show that water leaching at 90 ℃ for 5 h with liquid-solid ratio of 3∶1 can result in the leaching rate of arsenic up to 97.96% and the leaching rate of antimony just 0.72%. The obtained leaching residue only contains 0.09% arsenic, presenting effective separation between antimony and arsenic. With calcium and arsenic in a molar ratio of 1.43, hydrothermal reaction at 170 ℃ for 2 h can lead to an arsenic precipitation rate up to 99.68% and the solution after precipitation with arsenic and alkali in a mass ratio of 1.65‰, also presenting a good separation effect. Finally, the concentration and crystallization process by evaporation can generate crystalized alkali containing only 0.14‰ arsenic, which can meet the technical requirement for alkali in antimony refining.

arsenic-alkali slag  /  hydrothermal reaction  /  arsenic precipitation  /  antimony  /  water leaching  /  crystalized alkali
Dongsheng KANG, Guizhong JIN, Zhifeng XU, Yudong YANG, Yuhu LI, Chengyong JIN, Shen LUO. Recovery of Antimony and Alkali from Arsenic-Alkali Slag and Solidification of Arsenic[J]. Mining and Metallurgical Engineering, 2023 , 43 (4) : 125 -130 . DOI: 10.3969/j.issn.0253-6099.2023.04.027
Year 2023 volume 43 Issue 4
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Article Info
doi: 10.3969/j.issn.0253-6099.2023.04.027
  • Receive Date:2023-02-24
  • Online Date:2026-03-05
  • Published:2023-08-01
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  • Received:2023-02-24
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Affiliations
    1.Hsikwang Shan Twinkling Star Co Ltd, Lengshuijiang 417502, Hunan, China
    2.School of Metallurgical Engineering, Jiangxi University of Science and Technology, Ganzhou 341000, Jiangxi, China
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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