For the copper-containing acidic wastewater generated during underground mining process of a copper mine, a new processing technique consisting of copper recovery by replacement with iron filings, neutralization of alkaline tailings overflow, and treatment of coagulation and sedimentation was studied, and the effects of adding amount of iron filings, replacement reaction time and stirring speed on copper replacement rate were all investigated. And then, experiments on the proportion of required alkaline tailings overflow for neutralization of acidic wastewater and on toxicity characteristic leaching of neutralized sludge were performed, as well as the kinetics of replacement process was also studied. The results show that this new processing technique can produce sponge copper grading 35.6% Cu at 92.7% recovery, and the acidic wastewater after treatment can be up to the standard and directly discharged, with the cost of treatment agent at 0.95 yuan/t. Due to no hazardous waste generated, this processing technique can bring remarkable economic and environmental benefits.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |