Mo-Bi bulk concentrate is usually processed with a longer flowsheet at higher cost, and the traditional bismuth smelting processing technique also features longer flow, high energy consumption, as well as lower bismuth recovery. In order to solve those problems, an oxygen-rich hydrochloric acid leaching process was adopted in an experimental study on beneficiation of Mo-Bi bulk concentrate, and the effects of HCl concentration, leaching time and temperature on the leaching rates of Mo and Bi were investigated. It is shown that oxygen-rich hydrochloric acid leaching at 80 ℃ for 6.0 h, with HCl concentration of 3 mol/L, liquid/solid ratio of 3 ∶ 1, and stirring speed of 500 r/min, can result in the Bi leaching rate up to 99.13% and Mo left in the leaching residue. Thus, molybdenum and bismuth can be efficiently separated. The obtained leaching solution is then subjected to purification for purity removal and replacement with iron plate, and the finally obtained sponge bismuth can have purity exceeding 99%.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |