With sludge as the main raw material and corn straw as a carbon raiser, porous sludge-based activated carbon (PSAC) was prepared by adopting the ZnCl2 activation method. The adsorption performance of PSAC for removal of organic dye Rhodamine B (Rh B) was investigated, and the corresponding adsorption mechanism was also explored. Results indicate that PSAC has a rich pore structure, a high specific surface area (703.14 m2/g), and abundant oxygen-containing functional groups, with a point of zero charge (PZC) of 4.2. The adsorption kinetics of Rh B onto PSAC follows the Lagergren's pseudo-second-order kinetic model, and the adsorption isotherm is better fitted to the Langmuir equation. At 298 K, the saturated adsorption capacity of PSAC for Rh B reaches 196.08 mg/g. The adsorption process is dominated by chemical adsorption, and is spontaneous, endothermic and entropy-driven process. Electrostatic interaction, hydrogen bond interaction, π-π interaction and hydrophobic interaction all play certain roles in the adsorption process, among which electrostatic interaction is the main driving force.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |