A study was conducted on blank roasting and sulfuric acid leaching process for vanadium extraction from vanadium-bearing stone coal. Effects of ore sample particle size, roasting time, roasting temperature, sulfuric acid dosage, leaching time and leaching temperature on the vanadium extraction performance were investigated. Based on the optimized processing conditions, including sample with particle size of-0.15 mm, roasting temperature of 900 ℃, roasting time of 6 h, sulfuric acid dosage of 5%, liquid-solid ratio of 2 mL/g and stirring leaching at room temperature for 3 h, a scale-up verification experiment was conducted with increased ore sample feed. As a result, a vanadium leaching rate was 78.2%, and the main impurities and corresponding contents in the stock solution were found to be as follows:Fe 0.154 g/L, Al 0.578 g/L and Si 0.617 g/L. It is found that blank roasting effectively reduces sulfuric acid consumption and results in low impurity contents in the leaching solution, thus reducing difficulty in subsequent impurity removal process.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |