More and more technology-based enterprises are frequently adopting open science practices. According to traditional economic theory, open science has always been the behavioral norm and value principle of universities and research institutions, while the open science behavior of enterprises may reduce the benefits they obtain from innovation monopoly. Faced with the active phenomenon of open science in enterprises and the insufficient explanatory power of traditional theories, it is particularly necessary and urgent to study the logic and rationality of open science behavior in enterprises. On the basis of literature review, this article adopts a combination of bibliometric and manual coding methods. Through the analysis of relevant literature in the Web of Science database, it is found that: (1) research on open science in enterprises is shifting from phenomenon focus to mechanism cognition; (2) The open science behavior of enterprises can be interpreted from three behavioral logics, namely scientific research driven logic, market competition driven logic, and collective innovation driven logic. (3) From the perspective of the internal mechanism of whether enterprises can gain competitive advantages in open science behavior, analyze and propose the rationality of the triple logic of open science behavior for enterprises. The research conclusion provides a more systematic perspective for a deeper understanding of the increasing number of enterprises engaging in open science behavior; To promote open innovation, policy references have been provided from a theoretical perspective.