To prepare epoxy resin-based composites with excellent comprehensive properties, this study synthesized dendritic nanosilica (DSiO2) via a dual-template method and applied them to modify epoxy resin (EP). The relationship between structure and property of the composites was investigated by Fourier transform infrared spectroscopy (FTIR), X-ray photoelectron spectroscopy (XPS), scanning electron microscopy (SEM), transmission electron microscopy (TEM), and nitrogen adsorption-desorption tests. The results indicate that after modification with the silane coupling agent Z-6040, DSiO2 exhibits excellent dispersibility in epoxy resin. As the mass fraction of DSiO2 increases from 0 to 0.9%, the onset curing temperature of the composite decreases from 160.7℃ to 111.3, and the peak temperature decreases from 196.3℃ to 159.6℃; the tensile strength increases from 24.2 MPa to 53.6 MPa, the elongation at break increases from 10.5% to 13.5%, and the Rockwell hardness increases from 85.1 to 91.5. Compared with the unmodified EP, the DSiO2/EP composites exhibit significantly increased storage modulus, a glass transition temperature (Tg) that shifts toward higher temperature, and enhanced thermal stability.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |