With the development of power electronic equipment toward high-frequency, miniaturization, and integration, the performance of traditional polypropylene (PP) film materials is gradually becoming insufficient to meet the requirements of modern capacitors for high electric strength, low dielectric loss, and long service life. To address this, the modified PP film materials with different grafting rates were prepared by grafting 4-methylstyrene onto polypropylene (PP) via an aqueous suspension grafting method, and the effect of grafting rate on their comprehensive properties was studied. The results show that the optimal swelling time and reaction time of grafting modification are 120 minutes and 150 minutes, respectively. With the increase of grafting rate, the heating melting curve tends to shift towards lower temperatures, while the cooling crystallization curve tends to shift towards higher temperatures. When the grafting rate is 0.88%, the modified PP exhibits the highest tensile strength and elongation at break, with the electric strength reaching a maximum value of 400.8 kV/mm, and the trap density reaching a maximum value of 9.52×1019 m-³·eV-1, which is nearly 3.8 times higher than the maximum trap energy level density of pure PP material.
| 科 Family | 属数 Number of genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) | 属 Genus | 种数 Number of species | 占总种数比例 Percentage of total species (%) |
|---|---|---|---|---|---|---|
| 鹅膏菌科Amanitaceae | 2 | 11 | 5.26 | 鹅膏菌属 Amanita | 10 | 4.78 |
| 小菇科 Mycenaceae | 2 | 12 | 5.74 | 丝盖伞属 Inocybe | 5 | 2.39 |
| 多孔菌科 Polyporaceae | 8 | 14 | 6.70 | 蜡蘑属 Laccaria | 5 | 2.39 |
| 红菇科 Russulaceae | 3 | 23 | 11.00 | 小皮伞属 Marasmius | 6 | 2.87 |
| 小菇属 Mycena | 11 | 5.26 | ||||
| 光柄菇属 Pluteus | 5 | 2.39 | ||||
| 红菇属 Russula | 17 | 8.13 | ||||
| 栓菌属 Trametes | 5 | 2.39 |