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Preparation and Properties of BPDA/ODA Polyimide Films with Micro-branched Crosslinked Structure
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Shuhao HAN, Han ZHOU, Jianhua WANG, Shengli QI, Guofeng TIAN, Dezhen WU
Insulating Materials | 2021, 54(11) : 94 - 99
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Insulating Materials | 2021, 54(11): 94-99
Polyimide Film Special Issue
Preparation and Properties of BPDA/ODA Polyimide Films with Micro-branched Crosslinked Structure
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Shuhao HAN, Han ZHOU, Jianhua WANG, Shengli QI, Guofeng TIAN, Dezhen WU
Affiliations
  • Key Laboratory of Carbon Fiber and Functional Polymers, Beijing University of Chemical Technology, Beijing 100029, China
Published: 2021-11-22 doi: 10.16790/j.cnki.1009-9239.im.2021.11.013
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Taking 1,3,5-tri(4-aminophenoxy) benzene (TAPOB) as crosslink agent, a micro-branched crosslinked structure was constructed in 3,3′,4,4′-biphenyltetracarboxylic dianhydride (BPDA) and 4,4′-diaminodiohenyl ether (ODA) polyimide (PI) film, and a series of PI films with different TAPOB content were prepared. The effects of TAPOB content on the mechanical properties, thermomechanical properties, dielectric properties, and water absorption were studied. The results show that the addition of TAPOB can improve the comprehensive properties of BPDA/ODA PI films significantly. The existence of crosslinked structure is conductive to improve the mechanical properties, decrease the coefficient of thermal expansion (CTE) and water absorption of the film, and the micro-branched structure has a certain effect on reducing the dielectric constant.

polyimide  /  film  /  micro-branched  /  crosslink
Shuhao HAN, Han ZHOU, Jianhua WANG, Shengli QI, Guofeng TIAN, Dezhen WU. Preparation and Properties of BPDA/ODA Polyimide Films with Micro-branched Crosslinked Structure[J]. Insulating Materials, 2021 , 54 (11) : 94 -99 . DOI: 10.16790/j.cnki.1009-9239.im.2021.11.013
Year 2021 volume 54 Issue 11
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Article Info
doi: 10.16790/j.cnki.1009-9239.im.2021.11.013
  • Receive Date:2021-04-30
  • Online Date:2026-03-23
  • Published:2021-11-22
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  • Received:2021-04-30
  • Revised:2021-05-21
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    Key Laboratory of Carbon Fiber and Functional Polymers, Beijing University of Chemical Technology, Beijing 100029, China
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https://castjournals.cast.org.cn/joweb/jycl/EN/10.16790/j.cnki.1009-9239.im.2021.11.013
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表12种不同金属材料的力学参数

Family
属数
Number of
genus
种数
Number of
species
占总种数比例
Percentage of
total species (%)

Genus
种数
Number of
species
占总种数比例
Percentage of total
species (%)
鹅膏菌科Amanitaceae 2 11 5.26 鹅膏菌属 Amanita 10 4.78
小菇科 Mycenaceae 2 12 5.74 丝盖伞属 Inocybe 5 2.39
多孔菌科 Polyporaceae 8 14 6.70 蜡蘑属 Laccaria 5 2.39
红菇科 Russulaceae 3 23 11.00 小皮伞属 Marasmius 6 2.87
小菇属 Mycena 11 5.26
光柄菇属 Pluteus 5 2.39
红菇属 Russula 17 8.13
栓菌属 Trametes 5 2.39
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